1173179-78-6

Basic information

• Product Name: (S)-1-phenylethane-1,2-diyl bis(4-nitrobenzoate)
• CAS NO: 1173179-78-6
• Molecular Weight: 436.378
• Mol File: 1173179-78-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-phenylethane-1,2-diyl bis(4-nitrobenzoate)(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-phenylethane-1,2-diyl bis(4-nitrobenzoate)(1173179-78-6)
• EPA Substance Registry System: (S)-1-phenylethane-1,2-diyl bis(4-nitrobenzoate)(1173179-78-6)

Safety Data

• Hazardous Substances Data: 1173179-78-6(Hazardous Substances Data)

Upstream product

• 25779-13-9 (S)-1-phenyl-1,2-ethanediol 
• 122-04-3 4-nitro-benzoyl chloride 

Relevant articles and documents

Influence of α-methyl substitution of proline-based organocatalysts on the asymmetric α-oxidation of aldehydes

The direct asymmetric organocatalytic α-oxidation of aldehydes using trans-2-(p-methylphenylsulfonyl)-3-phenyloxaziridine is reported. This method affords the S isomer of α-hydroxy aldehydes, thereby complementing the selectivity for the R isomer observed using the two-step nitrosobenzene method. Use of α-methylproline and α-methylproline tetrazole significantly increases the enantioselectivity observed for the α-oxidation of aldehydes compared to analogous unsubstituted organocatalysts.