117319-07-0Relevant academic research and scientific papers
The Co-ordination of Small Molecules By Manganese(II) Phosphine Complexes. Part 14. Some Novel Mixed Tertiary Phosphine-t-Butyl Isocyanide Complexes of Manganese(II): t)(PPhMe2)> and t)4(PR3)2>2+ (PR3=PPhMe2, PPh2Me, PPhEt2, or PPrn3), and the X-Ray Crystal ...
Beagley, Brian,Benson, Christopher G.,Gott, George A.,McAuliffe, Charles A.,Pritchard, Robin G.,Tanner, S. Peter
, p. 2261 - 2266 (1988)
The complex t)(PPhMe2)> has been prepared by reaction of with CNBut.In ethanol solution rearrangement occurs to give the complex t)4(PPhMe2)2> and this reacts with other phosphines to yield t)4(PR3)2>2+ (PR3=PPrn3, PPhEt2, or PPh2Me).Air oxidation of an ethanol solution of t)4(PPhMe2)2>2+ produces red crystals of t)4(PPhMe2)2>2 the structure of which is reported.In the cation MnII is octahedrally co-ordinated and lies on a crystallographic inversion centre.The latter also relates each pair of anions which have MnII in tetrahedral co-oordination.The Mn-P bonds of the cation are rather short at 2.344(3) Angstroem whereas all other cation and anion dimensions are unremarkable.
