The Co-ordination of Small Molecules By Manganese(II) Phosphine Complexes. Part 14. Some Novel Mixed Tertiary Phosphine-t-Butyl Isocyanide Complexes of Manganese(II): t)(PPhMe2)> and t)4(PR3)2>2+ (PR3=PPhMe2, PPh2Me, PPhEt2, or PPrn3), and the X-Ray Crystal ...

DOI: 10.1039/DT9880002261

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2261 - 2266 (1988)

Update date:2022-08-04

Topics:

Authors:

Beagley, Brian

Benson, Christopher G.

Gott, George A.

McAuliffe, Charles A.

Pritchard, Robin G.

Tanner, S. Peter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9880002261

The complex t)(PPhMe2)> has been prepared by reaction of with CNBu^t.In ethanol solution rearrangement occurs to give the complex t)4(PPhMe2)2> and this reacts with other phosphines to yield t)4(PR3)2>²⁺ (PR3=PPrⁿ3, PPhEt2, or PPh2Me).Air oxidation of an ethanol solution of t)4(PPhMe2)2>²⁺ produces red crystals of t)4(PPhMe2)2>2 the structure of which is reported.In the cation Mn^II is octahedrally co-ordinated and lies on a crystallographic inversion centre.The latter also relates each pair of anions which have Mn^II in tetrahedral co-oordination.The Mn-P bonds of the cation are rather short at 2.344(3) Angstroem whereas all other cation and anion dimensions are unremarkable.

Full text of DOI:10.1039/DT9880002261

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{PPh₃(cyclo-C₆H₁₁)}tribromo(dimethylphenylphosphine oxide) manganese(II)

Cas No:117319-07-0

R&D Labs maybe for 117319-07-0

NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China
Zhejiang Quzhou Jiancheng Silicone Co., Ltd.(Shanghai Jiancheng Industial and Trade Co, Ltd)

Contact:18957018777 +86-570-3888777

Address:The company production base address： Quzhou City, Zhejiang Province high-tech industrial park Nianhua Road 37
Hubei Danao Pharmaceutical Co.,Ltd.

website:http://www.danaopharm.com

Contact:+86-719-5251167

Address:Fandan Road,Danjiangkou,Hubei

Relevant to this article

The heteroleptic complexes containing 2,3-diphenylquinoline derivatives as phosphorescent materials

Doi:10.1016/j.jpcs.2007.10.126
(2008)
REACTION BETWEEN GLYCAL BENZYL ETHERS AND THALLIUM(III) NITRATE. SYNTHESIS OF SHOWDOMYCIN ANALOGUES.

Doi:10.1016/S0040-4039(00)82059-6
(1988)
An efficient method for synthesis of pyrano[3,2-c]pyridine derivatives under microwave irradiation

Doi:10.1002/jhet.152
(2009)
Versatile reactivity of a zwitterionic isolable silylene toward ketones: Silicon-mediated, regio- and stereoselective C-H activation

Doi:10.1002/chem.200900318
(2009)
Components of ether-insoluble resin glycoside (Rhamnoconvolvulin) from rhizoma jalapae braziliensis

Doi:10.1248/cpb.57.262
(2009)
AXIALLY DISSYMMETRIC bis(AMINOPHOSPHINE)S DERIVED FROM 2,2 prime -DIAMINO-1,1 prime -BINAPHTHYL. SYNTHESIS AND APPLICATION TO RHODIUM(I)-CATALYZED ASYMMETRIC HYDROGENATIONS.

Doi:10.1246/bcsj.57.2171
(1984)

Article Doi