1173915-06-4

Basic information

• Product Name: 1,4-bis(4-methoxyphenylthio)-2,3,5,6-tetrafluorobenzene
• Synonyms: 1,4-bis(4-methoxyphenylthio)-2,3,5,6-tetrafluorobenzene
• CAS NO: 1173915-06-4
• Molecular Weight: 426.456
• Mol File: 1173915-06-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,4-bis(4-methoxyphenylthio)-2,3,5,6-tetrafluorobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-bis(4-methoxyphenylthio)-2,3,5,6-tetrafluorobenzene(1173915-06-4)
• EPA Substance Registry System: 1,4-bis(4-methoxyphenylthio)-2,3,5,6-tetrafluorobenzene(1173915-06-4)

Safety Data

• Hazardous Substances Data: 1173915-06-4(Hazardous Substances Data)

Upstream product

• 363-72-4 Pentafluorobenzene 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 696-63-9 4-Methoxybenzenethiol 
• 392-56-3 Hexafluorobenzene 
• 98098-60-3 S-(4-methoxyphenyl) 4-methoxybenzothioate 
• 98111-31-0 S-(4-methoxyphenyl) 3-phenylpropanethioate 
• 1258145-50-4 S-(4-methoxyphenyl) adamantan-1-ylthioate 
• 1258145-49-1 C₁₈H₂₆O₂S 
• 1258145-48-0 C₁₇H₂₆O₂S 
• 1258145-47-9 S-(4-methoxyphenyl) 4-chlorobenzothioate 
• 1258145-46-8 S-(4-methoxyphenyl) 4-(dimethylamino)benzenecarbothioate 
• 1258145-45-7 C₁₆H₁₆O₄S 

Relevant articles and documents

The thiolation of pentafluorobenzene with disulfides by C-H, C-F bond activation and C-S bond formation

A metal-free thiolation reaction between pentafluorobenzene and disulfides by C-H, C-F bond activation and C-S bond formation is reported. Bisthiolated tetrafluorobenzene derivatives would be prepared in moderate to good yields from pentafluorobenzene and disulfides under mild conditions. A possible mechanism for the reaction was given.

Copper-catalyzed direct thiolation of pentafluorobenzene with diaryl disulfides or aryl thiols by C-H and C-F bond activation

A Cu-catalyzed cross-coupling reaction of diaryl disulfides or aryl thiols with pentafluorobenzene using CuBr as the catalyst, tBuOLi or tBuOK as the base in DMSO at 60 °C under an O2 atmosphere was investigated. The corresponding bisarylthiola