98098-60-3

Basic information

• Product Name: Benzenecarbothioic acid, 4-methoxy-, S-(4-methoxyphenyl) ester
• Synonyms: Benzenecarbothioic acid,4-methoxy-,S-(4-methoxyphenyl) ester;4-methoxy-thiobenzoic acid S-(4-methoxy-phenyl ester);S-(4-methoxyphenyl) 4-methoxybenzothioate;4-Methoxy-thiobenzoesaeure-S-(4-methoxy-phenylester)
• CAS NO: 98098-60-3
• Molecular Formula: C15H14O3S
• Molecular Weight: 274.34
• Mol File: 98098-60-3.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, 4-methoxy-, S-(4-methoxyphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, 4-methoxy-, S-(4-methoxyphenyl) ester(98098-60-3)
• EPA Substance Registry System: Benzenecarbothioic acid, 4-methoxy-, S-(4-methoxyphenyl) ester(98098-60-3)

Safety Data

• Hazardous Substances Data: 98098-60-3(Hazardous Substances Data)

Upstream product

• 696-63-9 4-Methoxybenzenethiol 
• 123-11-5 4-methoxy-benzaldehyde 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 82102-37-2 9-methyl-9H-fluorene-9-carbonyl chloride 
• 201230-82-2 carbon monoxide 
• 622-29-7 N-Benzylidenemethylamine 
• 100-07-2 4-methoxy-benzoyl chloride 
• 696-62-8 para-iodoanisole 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 

Downstream Products

• 7291-00-1 N,N-dimethyl-4-methoxybenzamide 
• 1388470-24-3 (4-(2-hydroxyphenyl)piperazin-1-yl)(4-methoxyphenyl)methanone 
• 19486-73-8 N-tert-butyl-4-methoxybenzamide 
• 315248-36-3 4-methoxy-N-(4-nitrobenzyl)benzamide 
• 1422008-22-7 tert-butyl N-(3-(4-methoxybenzamido)propyl)carbamate 
• 1173915-06-4 1,4-bis(4-methoxyphenylthio)-2,3,5,6-tetrafluorobenzene 
• 701-53-1 p-methoxybenzoyl fluoride 

Relevant articles and documents

Visible-Light-Mediated Cross Dehydrogenative Coupling of Thiols with Aldehydes: Metal-Free Synthesis of Thioesters at Room Temperature

Thioesters play a crucial role in biological systems and serve as important building blocks for organic synthesis. Herein, Eosin Y and TBHP mediated photochemical cross dehydrogenative coupling (PCDC) between feedstock aldehydes and thiols has been descri

Polymer supported Pd catalyzed thioester synthesis via carbonylation of aryl halides under phosphine free conditions

A new polymer supported phosphine free Pd(ii) complex has been synthesized and characterized. The catalytic performance of the complex has been tested for the carbonylation of aryl halides into aryl thioesters under mild reaction conditions. Thioesters were obtained in excellent yields from various aryl iodides and thiols in the presence of carbon monoxide and polymer supported palladium catalyst. The effects of solvent, base, reaction time and catalyst amount for the thioester synthesis were reported. This catalyst showed excellent catalytic activity and recyclability. The polymer supported Pd(ii) catalyst could be easily recovered by filtration and reused more than five times without appreciable loss of its initial activity.

Pd-catalyzed thiocarbonylation with stoichiometric carbon monoxide: Scope and applications

A general protocol for the Pd-catalyzed thiocarbonylation of aryl iodides with stoichiometric carbon monoxide has been established employing a catalytic system composed of Pd(OAc)2 and DPEphos with low catalyst loading (1 mol %). Both electron-rich and -deficient aryl iodides proved effective for these couplings with aryl and alkyl thiols. The choice of the metal ligands and the solvent system was crucial for the efficiency and chemoselectivity of these transformations.