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4-methyl-1-(2-phenyl-1,2,3,4-tetrahydroisoquinolin-1-yl)pentan-2-one is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1174219-82-9

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1174219-82-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1174219-82-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,7,4,2,1 and 9 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1174219-82:
(9*1)+(8*1)+(7*7)+(6*4)+(5*2)+(4*1)+(3*9)+(2*8)+(1*2)=149
149 % 10 = 9
So 1174219-82-9 is a valid CAS Registry Number.

1174219-82-9Downstream Products

1174219-82-9Relevant articles and documents

A highly efficient gold-catalyzed oxidative C-C coupling from C-H bonds using air as oxidant

Xie, Jin,Li, Huamin,Zhou, Jiecong,Cheng, Yixiang,Zhu, Chengjian

, p. 1252 - 1255 (2012)

A breath of fresh air: The title reaction has been developed for the coupling of amines with nitroalkanes and different unmodified ketones using air as the sole oxidant under mild reaction conditions. The safe, convenient, and environmentally benign proce

The Photocatalyst-Free Cross-Dehydrogenative Coupling Reaction Enabled by Visible-Light Direct Excitation of Substrate

Guo, Xuan,Shao, Bing-Ru,Jiang, Wen-Feng,Shi, Lei

, p. 15743 - 15752 (2021/11/16)

A new photocatalyst-free strategy for the cross-dehydrogenative C-C and C-P coupling reaction has been described. This protocol provides a concise method to synthesize various 1-substituted tetrahydroisoquinoline (THIQ) derivatives enabled by visible-ligh

CuMgAl hydrotalcite as an efficient bifunctional catalyst for the cross-dehydrogenative C–C coupling reactions under mild conditions

Zhou, Weiyou,Lu, Wangmingzhu,Wang, Hui,Xia, Zhenzhen,Zhai, Shaoyan,Zhang, Zhong,Ma, Yuanjun,He, Mingyang,Chen, Qun

, (2020/08/24)

CuMgAl layered double hydroxide compounds (CuMgAl-LDHs) have been synthesized, characterized and investigated in the aerobic CDC reactions. The results indicated that NH3·H2O coprecipitated CuMgAl LDH (N-CuMgAl-LDH) was able to effic

Cross-dehydrogenative C(sp3)-C(sp3) coupling: Via C-H activation using magnetically retrievable ruthenium-based photoredox nanocatalyst under aerobic conditions

Rana, Pooja,Gaur, Rashmi,Gupta, Radhika,Arora, Gunjan,Jayashree,Sharma, Rakesh Kumar

supporting information, p. 7402 - 7405 (2019/06/27)

In the present work, we report the fabrication of a highly versatile ruthenium-based magnetically recoverable photoredox nanocatalyst with a large surface area. This visible light harvesting nanocatalyst was effectively used for cross-dehydrogenative coup

Bifunctional organic sponge photocatalyst for efficient cross-dehydrogenative coupling of tertiary amines to ketones

Zhang, Teng,Liang, Weiwei,Huang, Yuxing,Li, Xingrong,Liu, Yizhen,Yang, Bo,He, Chuanxin,Zhou, Xuechang,Zhang, Junmin

supporting information, p. 12536 - 12539 (2017/11/30)

A novel bifunctional organic sponge photocatalyst can enable the efficient coupling of tertiary amines with ketones in water. The asymmetric transformation can be also achieved by using this sponge photocatalyst.

Aerobic oxidative Mannich reaction promoted by catalytic amounts of stable radical cation salt

Huo, Congde,Wu, Mingxia,Jia, Xiaodong,Xie, Haisheng,Yuan, Yong,Tang, Jing

, p. 9860 - 9864 (2015/01/09)

A catalytic amount of triarylaminium salt is demonstrated to be an efficient initiator for oxidative Mannich reaction of tertiary amines and nonactivated ketones under mild neutral conditions. Air is essential for this reaction and acts as a terminal oxid

Molecular iodine catalyzed cross-dehydrogenative coupling reaction between two sp3 C-H bonds using hydrogen peroxide

Nobuta, Tomoya,Tada, Norihiro,Fujiya, Akitoshi,Kariya, Atsumasa,Miura, Tsuyoshi,Itoh, Akichika

supporting information, p. 574 - 577 (2013/04/10)

A useful method for molecular iodine catalyzed oxidative C-C bond formation between tertiary amines and a carbon nucleophile using hydrogen peroxide as the terminal oxidant is reported. This is the first report of a molecular iodine catalyzed cross-dehydrogenative coupling (CDC) reaction between two sp 3 C-H bonds.

CDC reactions of N-aryl tetrahydroisoquinolines using catalytic amounts of DDQ: C-H activation under aerobic conditions

Alagiri, Kaliyamoorthy,Devadig, Pradeep,Prabhu, Kandikere R.

supporting information; experimental part, p. 5160 - 5164 (2012/05/20)

An oxidative cross-dehydrogenative coupling (CDC) reaction for the formation of C-C and C-P bonds is disclosed using a catalytic amount of DDQ (10 mol %) under aerobic conditions (see scheme). This unprecedented environmentally benign strategy of using AI

Oxidative coupling of amines and ketones by combined vanadium- and organocatalysis

Sud, Abhishek,Sureshkumar, Devarajulu,Klussmann, Martin

supporting information; experimental part, p. 3169 - 3171 (2009/12/01)

The combination of vanadium- and organocatalysis allows for the direct oxidative coupling of cyclic tertiary amines with non-activated ketones without the need for preformed leaving groups.

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