117606-87-8

Upstream product

• 100-52-7 benzaldehyde 
• 123-34-2 3-allyloxy-1,2-propanediol 
• 909701-53-7 (R)-(2-phenyl-1,3-dioxolan-4-yl)methanol 
• 106-95-6 allyl bromide 
• 1708-39-0 (S)-1,2-O-benzylideneglycerol 

Downstream Products

• 117606-90-3 (R)-1-O-allyl-3-O-benzylglycerol 
• 106401-57-4 1-O-allyl-2-O-benzyl-sn-glycerol 
• 117606-88-9 (S)-1-O-allyl-3-O-benzylglycerol 

Relevant academic research and scientific papers

Chemistry of dioxacyclanes: XI. Synthesis and properties of unsaturated derivatives of 1,3-dioxolanes

1,3-Dioxolanes were synthesized by reactions of 3-cyclohexenecarboxaldehyde and 5-norbornene2-endo-carboxaldehyde with 1,2-ethanedithiol and 3-(2-propenyloxy)- and 3-propoxy-1,2-propanediols, as well as of propionaldehyde, benzaldehyde, and trichloroaceta

Chemistry of dioxacyclanes: VII.1 Synthesis of 1,3-dioxolane derivatives from 3-(2-propenyloxy)propane-1,2-diol and their properties

2,4-Disubstituted 1,3-dioxolanes were synthesized by reactions of benzaldehyde and its parachloro derivatives, as well as 3-cyclohexenecarboxaldehyde with 3-(2-propenyloxy)-1,2-propanediol. The products were brought into bromination, dichlorocarbene addition, and epoxidation reactions. It is found that when both components of the heterogeneous reaction of dioxolane ring formation have a double bond, the acid catalyst in strongly deactivated.

The Chemistry of L-Ascorbic and D-Isoascorbic Acids. 2. R and S Glyceraldehydes from a Common Intermediate

(R)- and (S)-glyceraldehyde and glycerol derivatives have been prepared from (2R,3S)-1,2-O-isopropylidenebutane-1,2,3,4-tetrol. (2R,3S)- and (2S,3S)-1,2-O-benzylidenebutane-1,2,3,4-tetrol have been prepared and cleaved to give (R)- and (S)-1,2-O-benzylideneglyceraldehydes and -glycerols.The conservation of chirality and conversion to PAF analogues are also demonstrated.