1176166-43-0Relevant academic research and scientific papers
Expanded-ring and backbone-functionalised N-heterocyclic carbenes
Iglesias, Manuel,Beetstra, Dirk J.,Cavell, Kingsley J.,Dervisi, Athanasia,Fallis, Ian A.,Kariuki, Benson,Harrington, Ross W.,Clegg, William,Horton, Peter N.,Coles, Simon J.,Hursthouse, Michael B.
scheme or table, p. 1604 - 1607 (2010/09/06)
An unsaturated seven-membered amidinium salt 7 decomposes in the presence of metal salts under basic conditions. However, 7 readily forms a Diels-Alder cycloadduct with CpH from which the RhI complexes may be prepared. Thus, structurally elabor
Six- and seven-membered ring carbenes: Rational synthesis of amidinium salts, generation of carbenes, synthesis of Ag(I) and Cu(I) complexes
Kolychev, Eugene L.,Portnyagin, Ivan A.,Shuntikov, Viacheslav V.,Khrustalev, Victor N.,Nechaev, Mikhail S.
experimental part, p. 2454 - 2462 (2009/10/09)
Reactions of neat 1,3- and 1,4-dibromides with N,N′-diarylformamidines in the presence of diisopropylethylamine (DIPEA) afford corresponding amidinium salts in high yields (>80%). Six- and seven-membered ring amidinium salts bearing bulky Mes (2,4,6-Mesu
