117632-89-0Relevant academic research and scientific papers
Iodobenzene and m-chloroperbenzoic acid mediated oxidative dearomatization of phenols
Taneja, Neha,Peddinti, Rama Krishna
, p. 3958 - 3963 (2016/08/11)
Oxidative dearomatization of 2- and 4-substituted phenols to their corresponding benzoquinone monoketals by catalytic amount of iodobenzene, and m-CPBA as a co-oxidant has been achieved via in situ generation of PhIO2, a hypervalent iodine(V) s
Direct synthesis of anilines and nitrosobenzenes from phenols
St Amant,Frazier,Newmeyer,Fruehauf,Read De Alaniz
supporting information, p. 5520 - 5524 (2016/07/06)
A one-pot synthesis of anilines and nitrosobenzenes from phenols has been developed using an ipso-oxidative aromatic substitution (iSOAr) process. The products are obtained in good yields under mild and metal-free conditions. The leaving group effect on reactions that proceed through mixed quionone monoketals has also been investigated and a predictive model has been established.
Oxidation with hypervalent iodine reagents. Part II: Novel cyclohexadienones as precursors for the synthesis of anthraquinones
Mitchell, Anthony S.,Russell, Richard A.
, p. 4387 - 4410 (2007/10/03)
The oxidation of substituted phenols with phenyliodonium diacetate in methanol was found to afford 2,4-cyclohexadienones, 2,5-cyclohexadienones or mixtures of isomers, depending on the substrate being oxidized. Annulation of these cyclohexadienones with the anion of 3-cyanophthalide afforded anthraquinones in high yields.
Oxidations Of Substituted Phenols With Hypervalent Iodine : Applications To The Phthalide Annulation Route To Anthraquinones
Mitchell, Anthony S.,Russell, Richard A.
, p. 545 - 548 (2007/10/02)
Substituted phenols are oxidized by phenyliodonium diacetate in methanol to yield either cyclohexa-2,4-dienones or the isomeric 2,5-dienones depending upon the structure of the phenol.Annulation of these oxidation products with the anion of 3-cyanophthali
