117666-33-8

Upstream product

• 142387-43-7 racemic 2,4-di-O-benzyl-5,6-O-isopropylidene-myo-inositol 
• 142436-10-0 (1S,2S,3R,4R,5S,6R)-3,5-Bis-allyloxy-4,6-bis-benzyloxy-cyclohexane-1,2-diol 
• 136091-44-6 (+/-)-1,3-Di-O-allyl-2,6-di-O-benzyl-myo-inositol 
• 142387-49-3 (1S,2S,3R,4S,5R,6R)-3,5-Bis-benzyloxy-4,6-bis-[((E)-propenyl)oxy]-cyclohexane-1,2-diol 
• 142436-05-3 1D-2,6-di-O-benzyl-1,5-di-O-p-methoxybenzyl-myo-inositol 
• 117666-30-5 (+/-)-1,3,4,5-tetra-O-allyl-2,6-di-O-benzyl-myo-inositol 
• 136986-14-6 1D-1,3,4,5-tetra-O-allyl-myo-inositol 
• 142387-47-1 C₅₆H₆₄O₁₄ 
• 142387-51-7 4,5-bis-(-)-ω-camphanate 1D-1,3-di-O-allyl-2,6-di-O-benzyl-myo-inositol 
• 142387-48-2 (+/-)-1,3-di-O-allyl-2,6-di-O-benzyl-4,5-O-isopropylidene-myo-inositol 
• 136986-30-6 (3aR,4S,5R,6S,7S,7aR)-5,7-Bis-allyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxole-4,6-diol 
• 117666-30-5 (+)-1,3,4,5-tetra-O-allyl-2,6-di-O-benzyl-myo-inositol 
• 136986-14-6 (+/-)-1,3,4,5-tetra-O-allyl-myo-inositol 
• 130296-31-0 1,3-Di-O-allyl-myo-inositol 

Downstream Products

• 115015-98-0 octabenzyl 1D-2,6-di-O-benzyl-myo-inositol 1,3,4,5-tetrakisphosphate 

Relevant academic research and scientific papers

The preparation and phosphorylation of 2,5- and 1D-2,6-di-O-benzyl-myo-inositol

1,3,4,6-Tetra-O-allyl-myo-inositol was converted into the 2,5-di-O-benzyl- and 2,5-di-O-p-methoxybenzyl ethers, and the products were deallylated to give the 2,5-di-O-benzyl (and p-methoxybenzyl) ethers of myo-inositol, which were converted into the mono-

TOTAL SYNTHESIS OF OPTICALLY ACTIVE MYO-INOSITOL 1,4,5-TRISPHOSPHATE AND MYO-INOSITOL 1,3,4,5-TETRAKISPHOSPHATE

A convenient approach to the preparation of the title compounds illustrating selective protection, optical resolution and phosphorylation is presented.