1177249-19-2

Upstream product

• 109-72-8 n-butyllithium 
• 67251-69-8 N,N-dimethylaminoferrocene 
• 109-63-7 boron trifluoride diethyl etherate 
• 16523-54-9 chlorodicyclohexylphosphane 
• 1262899-10-4 (S)-(-)-2-dicyclohexylphosphinothioyl-1-dimethylaminoferrocene 

Downstream Products

• 1177249-23-8 dichloro(2-dicyclohexylphosphino-1-dimethylaminoferrocene-κN,P)platinum(II) 
• 1262899-37-5 (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene iridium(cyclooctadiene) chloride 

Relevant academic research and scientific papers

Asymmetric hydrogenation of alkenes with planar chiral 2-phosphino-1- aminoferrocene-iridium(I) complexes

The first highly enantioenriched and enantiopure planar chiral 2-phosphino-1-aminoferrocene ligands and their Ir(COD)BArF complexes are reported. The ligands display bidentate coordination behavior towards iridium, as indicated by trends in 31P and 1H NMR spectra of the phosphine moieties and the α to nitrogen substituents of the amines. All of the new complexes showed good reactivity as catalysts in promoting asymmetric hydrogenation of several prochiral alkenes, with enantioselectivities up to 92%. Iridium complexes of dimethylaminoferrocene derivatives containing P-Ar groups [PPh2 and P(o-tol)2] gave the highest levels of asymmetric induction.

Palladium(II), platinum(II), and iridium(I) complexes of 2-phosphino-1-dimethylaminoferrocenes: A survey of structure and catalysis

A series of PdCl2, PtCl2, and Ir(COD)BArF complexes bearing a rare class of racemic bidentate 2-phosphino-1- dimethylaminoferrocene ligands were prepared and characterized by NMR spectroscopy and X-ray crystallography. The