117839-39-1

Basic information

• Product Name: 6-methoxy-4-methyl-2-(p-tolyl)quinoline
• Synonyms: 6-methoxy-4-methyl-2-(p-tolyl)quinoline
• CAS NO: 117839-39-1
• Molecular Weight: 263.339
• Mol File: 117839-39-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 6-methoxy-4-methyl-2-(p-tolyl)quinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 6-methoxy-4-methyl-2-(p-tolyl)quinoline(117839-39-1)
• EPA Substance Registry System: 6-methoxy-4-methyl-2-(p-tolyl)quinoline(117839-39-1)

Safety Data

• Hazardous Substances Data: 117839-39-1(Hazardous Substances Data)

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 104-94-9 4-methoxy-aniline 
• 108-03-2 1-Nitropropane 
• 84666-28-4 4-Chloromethyl-6-methoxy-2-p-tolyl-quinoline 
• 84666-27-3 2-(p-tolyl)-6-methoxy-4-quinolinemethanol 
• 18193-09-4 2-(p-tolyl)-6-methoxy-4-quinolinecarboxylic acid 
• 84666-26-2 (6-Methoxy-2-p-tolyl-quinolin-4-yl)-methanesulfonyl chloride 
• 462628-12-2 4-[2-((1R,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-ethoxymethyl]-6-methoxy-2-p-tolyl-quinoline 
• 462628-11-1 6-methoxy-4-octyloxymethyl-2-p-tolyl-quinoline 
• 462628-10-0 6-methoxy-4-(3-phenyl-propoxymethyl)-2-p-tolyl-quinoline 
• 462628-09-7 4-(4-chloro-phenoxymethyl)-6-methoxy-2-p-tolyl-quinoline 
• 462628-08-6 6-methoxy-4-phenoxymethyl-2-p-tolyl-quinoline 

Relevant articles and documents

Facile synthesis of substituted quinolines by iron(iii)-catalyzed cascade reaction between anilines, aldehydes and nitroalkanes

A library of substituted quinolines has been synthesized by the reaction of aldehydes, anilines and nitroalkanes using a catalytic amount of Fe(iii) chloride. The reaction is a simple, efficient, one-pot, three-component domino strategy in ambient air which afforded the products in high yields. A probable pathway of the reaction is a sequential aza-Henry reaction/cyclization/denitration. The use of commercially available chemicals as starting materials, an inexpensive metal catalyst, aerobic reaction conditions, tolerance of a wide range of functional groups, and operational simplicity are the notable advantages of this present protocol.

Approaches to a photocleavable protecting group for alcohols

A new protecting group for the alcohol functionality was devised and shown to be removed photochemically under ultraviolet light in the presence of a radical scavenger in high yields.

A NEW PHOTOCHEMICALLY REMOVABLE PROTECTING GROUP FOR AMINES

A new arylmethylsulfonyl chloride reacts with secondary or primary amines to give sulfonamides which can be photochemically cleaved, making it suitable for use as a photoremovable protecting group.