117894-26-5Relevant articles and documents
Synergistic Cu-amine catalysis for the enantioselective synthesis of chiral cyclohexenones
Quintard,Rodriguez
supporting information, p. 9523 - 9526 (2015/06/08)
An unprecedented utilization of 1,3-acetonedicarboxylic acid as a 1,3-bis-pro-nucleophile and a reactive acetone surrogate in enantioselective catalysis has been reported. By synergistically activating the ketodiacid by copper catalysis and an α,β-unsatur
Asymmetric Ni-catalyzed conjugate allylation of activated enones
Sieber, Joshua D.,Morken, James P.
, p. 4978 - 4983 (2008/09/20)
The nickel-catalyzed enantioselective addition of allylboronic acid pinacol ester, allylB(pin), is described. This reaction is highly effective with dialkylidene ketones and favors the allylation of the benzylidene site in nonsymmetric substrates. The rea
A simple asymmetric organocatalytic approach to optically active cyclohexenones
Carlone, Armando,Marigo, Mauro,North, Chris,Landa, Aitor,Jorgensen, Karl Anker
, p. 4928 - 4930 (2007/10/03)
Optically active 2,5-disubstituted-cyclohexen-2-one derivatives have been prepared in a one-pot process consisting of five reaction steps: an organocatalytic asymmetric conjugated addition of β-ketoesters to α,β-unsaturated aldehydes that proceeds in aque