1180480-99-2Relevant academic research and scientific papers
Silylene oxonium ylides: di-tert-butylsilylene insertion into C-O bonds
Bourque, Laura E.,Haile, Pamela A.,Loy, Janice M.N.,Woerpel
scheme or table, p. 5608 - 5613 (2009/12/01)
Allylic ethers undergo insertions of silylenes into C-O bonds to form allylic silanes. Silylene insertion into C-O acetal bonds was also observed. Formation of silylene ylide intermediates led to [1,2]-Stevens rearrangement products as well as [2,3]-sigma
