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Metal-catalyzed silylene insertions of allylic ethers: Stereoselective formation of chiral allylic silanes
Bourque, Laura E.,Cleary, Pamela A.,Woerpel
, p. 12602 - 12603 (2008/09/16)
Silylene insertion into allylic ethers occurs suprafacially to provide enantioenriched allylic silanes and disilanes. Silylene insertion to a variety of protected allylic alcohols utilizing silver- and copper-mediated conditions proved to be a general method for allylic silane formation. Allylic disilanes reacted similarly to allylic silanes, undergoing both annulation and allylation reactions. Copyright
