118356-41-5

Upstream product

• 100-52-7 benzaldehyde 
• 143100-97-4 1-((2-(chloromethyl)allyl)sulfonyl)-4-methylbenzene 
• 16192-04-4 1-methyl-4-(2-methylallylsulfonyl)benzene 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 118356-18-6 1-methyl-1-(tosylmethyl)oxirane 
• 118356-32-4 (E)-3-methyl-1-phenyl-2-tosyl-2-butene-1,4-diol 

Relevant academic research and scientific papers

Dilithiated 2-(Chloromethyl)-3-tosylpropene: A New γ-Chlorinated Allyl Sulfone Dianion in Organic Synthesis

Dilithiation of 2-(chloromethyl)-3-tosylpropene (1) with n-butyllithium at -90 deg C in the presence of DMPU affords the allylic dianion 2 which reacts with deuterium oxide or very reactive alkylating agents to give α,α-disubstituted products 3 or 4, resp

Dilithiation of 2-(Chloromethyl)-3-tosylpropene: Synthesis and Reactivity of a New Chlorinated Allyl Sulfone Dianion

Double lithiation of 2-(chloromethyl)3-tosylpropene (4) with n-butyl-lithium at -90 deg C in the presence of DMPU leads to the dianion 5, which by reaction with deuterium oxide affords the corresponding 3,3-dideuteriated product 6.The alkylation reaction

Substituted Lithium (E)-3-Lithio-3-tosyl-2-propenolates: Useful Intermediates in Organic Synthesis

The lithiation of substituted tosylated epoxides 7 derived from allylic sulfones with methyllithium leads to lithium (E)-3-lithio-3-tosyl-2-propenolates 5 in a stereoselective manner.The further reaction of these intermediates with different electrophilic