118356-49-3Relevant academic research and scientific papers
Substituted Lithium (E)-3-Lithio-3-tosyl-2-propenolates: Useful Intermediates in Organic Synthesis
Najera, Carmen,Yus, Miguel
, p. 1491 - 1499 (2007/10/02)
The lithiation of substituted tosylated epoxides 7 derived from allylic sulfones with methyllithium leads to lithium (E)-3-lithio-3-tosyl-2-propenolates 5 in a stereoselective manner.The further reaction of these intermediates with different electrophilic
Dilithiated (E)-N-Isopropyl-3-tosylacrylamide: A New β-Acylvinyl Anion Equivalent in Organic Synthesis
Najera, Carmen,Yus, Miguel
, p. 1387 - 1391 (2007/10/02)
The dilithiated anion (6) obtained by reaction of (E)-N-isopropyl-3-tosylacrylamide with 2 equiv. of methyl-lithium at -78 deg C is a new and efficient β-acylvinyl anion equivalent useful in the synthesis of substituted 3-tosyl-α,β-butenolides (8) by reac
