118378-03-3

Basic information

• Product Name: (1S,5S,6R,8S)-5-Benzyloxymethyl-8-(1-hydroxy-1-methyl-ethyl)-bicyclo[4.2.0]octan-2-one
• Synonyms: (1S,5S,6R,8S)-5-Benzyloxymethyl-8-(1-hydroxy-1-methyl-ethyl)-bicyclo[4.2.0]octan-2-one
• CAS NO: 118378-03-3
• Molecular Weight: 302.414
• Mol File: 118378-03-3.mol

Chemical Properties

• CAS DataBase Reference: (1S,5S,6R,8S)-5-Benzyloxymethyl-8-(1-hydroxy-1-methyl-ethyl)-bicyclo[4.2.0]octan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5S,6R,8S)-5-Benzyloxymethyl-8-(1-hydroxy-1-methyl-ethyl)-bicyclo[4.2.0]octan-2-one(118378-03-3)
• EPA Substance Registry System: (1S,5S,6R,8S)-5-Benzyloxymethyl-8-(1-hydroxy-1-methyl-ethyl)-bicyclo[4.2.0]octan-2-one(118378-03-3)

Safety Data

• Hazardous Substances Data: 118378-03-3(Hazardous Substances Data)

Upstream product

• 75-16-1 methylmagnesium bromide 
• 573699-05-5 (-)-4-((Benzyloxy)methyl)-2-cyclohexen-1-one 
• 292638-85-8 acrylic acid methyl ester 
• 573699-36-2 2-((1R,2S,6S,7S)-2-Benzyloxymethyl-5,5-dimethoxy-bicyclo[4.2.0]oct-7-yl)-propan-2-ol 
• 573699-34-0 (1R,2S,6S,7S)-2-Benzyloxymethyl-5-oxo-bicyclo[4.2.0]octane-7-carboxylic acid methyl ester 
• 573699-35-1 (1R,2S,6S,7S)-2-Benzyloxymethyl-5,5-dimethoxy-bicyclo[4.2.0]octane-7-carboxylic acid methyl ester 
• 124665-51-6 2-((1R,2S,6S,7S)-2-Benzyloxymethyl-5,5-dimethoxy-bicyclo[4.2.0]oct-7-yl)-propan-2-ol 
• 124665-33-4 (1R,2S,6S,7S)-2-Benzyloxymethyl-5-oxo-bicyclo[4.2.0]octane-7-carboxylic acid methyl ester 
• 124665-50-5 (1R,2S,6S,7S)-2-Benzyloxymethyl-5,5-dimethoxy-bicyclo[4.2.0]octane-7-carboxylic acid methyl ester 

Downstream Products

• 573699-09-9 (1S,5S,6R,8S)-5-Benzyloxymethyl-8-(1-methoxymethoxy-1-methyl-ethyl)-bicyclo[4.2.0]octan-2-one 
• 118378-04-4 (1R,5R,6S,8R)-5-Benzyloxymethyl-8-(1-methoxymethoxy-1-methyl-ethyl)-bicyclo[4.2.0]octan-2-one 
• 118378-11-3 C₃₀H₃₆N₂O₄Se 
• 118378-12-4 C₂₉H₃₂N₂O₃Se 
• 118378-07-7 N-[(1R,2aR,3R,8bR)-3-Benzyloxymethyl-1-(1-methoxymethoxy-1-methyl-ethyl)-8-methyl-1,2,2a,3,4,8b-hexahydro-cyclobuta[a]naphthalen-7-yl]-benzamide 
• 124665-34-5 (1R,2aR,3R,4aS,8bR)-3-Benzyloxymethyl-1-(1-methoxymethoxy-1-methyl-ethyl)-8-methyl-1,2,2a,3,4,5,6,8b-octahydro-4aH-cyclobuta[a]naphthalen-7-one oxime 
• 118378-06-6 (1R,2aR,3R,4aS,8bR)-3-Benzyloxymethyl-1-(1-methoxymethoxy-1-methyl-ethyl)-8-methyl-1,2,2a,3,4,5,6,8b-octahydro-4aH-cyclobuta[a]naphthalen-7-one 
• 124665-31-2 (1R,2aR,3R,8bR)-3-Benzyloxymethyl-1-(1-methoxymethoxy-1-methyl-ethyl)-8-methyl-1,2,2a,3,4,8b-hexahydro-cyclobuta[a]naphthalen-7-ylamine 
• 124665-52-7 C₄₈H₆₇NO₇Si 
• 124665-42-5 C₄₈H₆₇NO₇Si 
• 124665-53-8 C₄₆H₆₅NO₇SSi 
• 124665-54-9 C₃₈H₄₇NO₆S 
• 124665-41-4 C₄₀H₅₉NO₆Si 
• 124665-40-3 C₃₉H₅₉NO₅Si 

Relevant articles and documents

Tremorgenic indole alkaloids. The total synthesis of (-)-penitrem D

A convergent, stereocontrolled total synthesis of the architecturally complex tremorgenic indole alkaloid (-)-penitrem D (4) has been achieved. Highlights of the synthesis include an efficient, asymmetric synthesis of the western hemisphere; the stereocon

A Concise Route to the Penitrem Series of Tremorgenic Mycotoxins: Preparation of an Oxocane-Fused Indole

In this paper we record an efficient synthesis of tricyclic aniline 4, an advanced intermediated which embodies the B-C-D rings of penitrem D (1).In addition, a diminutive version of the natural product, hexacycle 10, was prepared.