118451-60-8Relevant academic research and scientific papers
Antiproliferative activity of (η6-arene)ruthenacarborane sandwich complexes against HCT116 and MCF7 cell lines
Gozzi, Marta,Schwarze, Benedikt,Sárosi, Menyhárt-Botond,L?nnecke, Peter,Dra?a, Dijana,Maksimovi?-Ivani?, Danijela,Mijatovi?, Sanja,Hey-Hawkins, Evamarie
, p. 12067 - 12080 (2017)
Three [(η6-arene)RuC2B9H11] complexes (arene = p-cymene (2), biphenyl (3) and 1-Me-4-COOEt-C6H4 (4)) were synthesised according to modified literature procedures and fully characterised. 2-
Oxo-tethered ruthenium(II) complex as a bifunctional catalyst for asymmetric transfer hydrogenation and H2 hydrogenation
Touge, Taichiro,Hakamata, Tomohiko,Nara, Hideki,Kobayashi, Tohru,Sayo, Noboru,Saito, Takao,Kayaki, Yoshihito,Ikariya, Takao
supporting information; experimental part, p. 14960 - 14963 (2011/11/05)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high levels of enantioselectivity.
Ethynyl Ortho Esters as Precursors of Propargyl Cations. The Low-Temperature, Ionic Diels-Alder Addition of Ethyl Propiolate to 1,3-Dienes via Ethynyl Ortho Esters
Gassman, Paul G.,Chavan, Subhash P.
, p. 3407 - 3410 (2007/10/02)
3,3,3-Triethoxypropyne (triethyl orthopropiolate) was added to a series of 1,3-dienes at low temperature in the presence of trimethylsilyl triflate to yield the 4? + 2? products of the formal addition of ethyl propiolate to the 1,3-dienes.
