118468-43-2Relevant academic research and scientific papers
Synthesis and Reactions of 1-Thianaphthalenes
Hori, Mikio,Kataoka, Tadashi,Shimizu, Hiroshi,Aoki, Harumi
, p. 3816 - 3825 (2007/10/02)
Treatment of 1-methyl-4-phenyl-1-thio-2H-chromenium perchlorate (2) with sodium hydride yielded a dimeric compound 4 and two rearrangement products 5 and 6 via unstable 1-methyl-4-phenyl-1-thianaphthalene (3).On heating with potassium hydroxide in ethanol
Effects of Aryl Substituents on Electron-Transfer-Mediated Photochemical Addition of Alcohol to 1,1,2-Triarylcyclopropanes
Tomioka, Hideo,Inoue, Osamu
, p. 1404 - 1406 (2007/10/02)
Direct irradiation of 1,1,2-triarylcyclopropanes in alcohol resulted in the formation of all possible products arising from trimethylene biradicals, while DCB-sensitised irradiation gave a novel "anti-Markownikoff" addition product of alcohol almost exclusively.In order to get insight into the nature and fate of intermediates in the reactions, the effects of nucleophiles and aryl substituents are examined.
