1185-29-1Relevant articles and documents
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Souma et al.
, p. 2016 (1973)
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Hexacarbonyldiplatinum(I) cation-catalyzed carbonylation of olefins in concentrated sulfuric acid
Xu,Fujiwara,Tanaka,Souma
, p. 8105 - 8107 (2000)
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Creger,P.L.
, p. 2500 - 2501 (1967)
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CARBONYLATION OF OLEFINS AND ALCOHOLS AT ATMOSPHERIC PRESSURE IN THE PRESENCE OF ACID CATALYSTS WITH ADDED Ag2O OR Cu2O
Pirozhkov, S. D.,Stepanyan, A. S.,Myshenkova, T. N.,Ordyan, M. B.,Lapidus, A. L.
, p. 1852 - 1858 (1982)
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Method for the Production of Mixtures Containing Tertiary Isononanoic Acids Based on 2-Ethylhexanol
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Paragraph 0038, (2017/07/14)
A process for producing a mixture comprising tertiary isononanoic acids proceeding from 2-ethylhexanol is characterized in that 2-ethylhexanol is (a) reacted at a temperature of 0° C. to 40° C. with a mixture of concentrated formic acid and a concentrated Br?nsted acid, wherein 2 to 10 mol of formic acid are used per mole of 2-ethylhexanol and the concentrated Br?nsted acid is used in an amount that corresponds to 6 to 90 mol of protons per mole of 2-ethylhexanol. The resulting reaction mixture from step (a) is subsequently (b) brought into contact with water, and the mixture comprising tertiary isononanoic acids formed according to step b) is removed.
Sulfoximine assisted Pd(II)-catalyzed bromination and chlorination of primary β-C(sp3)-H bond
Rit, Raja K.,Yadav, M. Ramu,Ghosh, Koushik,Shankar, Majji,Sahoo, Akhila K.
supporting information, p. 5258 - 5261 (2015/01/09)
S-Methyl-S-2-pyridyl-sulfoximine (MPyS) directed bromination and chlorination of the 1°-β-C(sp3)-H bond of MPyS-N-amides is realized under the influence of N-Br/Cl-phthalimides and a Pd(II)-catalyst. The sequential halogenation and acetoxylation of α-dimethyl MPyS-N-amides constructs highly functionalized α-trisubstituted aliphatic acid derivatives. The MPyS directing group is cleaved from the halogenated products and recovered. (Chemical Equation Presented).