118506-84-6Relevant articles and documents
STANNYLATION REACTIONS AND CROSS-COUPLINGS IN PYRIMIDINES
Majeed, Amera J.,Antonsen, Oyvind,Benneche, Tore,Undheim, Kjell
, p. 993 - 1006 (2007/10/02)
Pyrimidines have been stannylated in the activated 4-position by thermal decarboxylation of the corresponding carboxylic organotin esters.The decarboxylation can be catalyzed by bis(acetonitrile)palladium(II) dichloride. 4-Iodopyrimidines are 4-stannylate
Palladium-Catalyzed Coupling of Organotin Reagents and Alkenes with 4-Iodopyrimidines
Solberg, Jan,Undheim, Kjell
, p. 712 - 716 (2007/10/02)
Palladium-catalyzed coupling with vinyltin reagent is a versatile and efficient method for the preparation of 4-vinylpyrimidines from substituted 4-iodopyrimidine.The alternative Heck coupling has been used when the vinyl group is conjugated to an electro