118619-11-7Relevant articles and documents
A new route to medium and large heterocyclic compounds
Ventrice, Tina,Campi, Eva M.,Jackson, W. Roy,Patti, Antonio F.
, p. 1463 - 1464 (1999)
Hydrogenation of nitrobenzenes bearing aldehyde-containing substituents over heterogeneous platinum or palladium catalysts gives medium and/or large heterocyclic amines as a result of simple or dimeric cyclisation in moderate to good yields; a range of he
A new strategy for synthesis of polymeric supports with triazene linkers
Lazny, Ryszard,Nodzewska, Aneta,Klosowski, Piotr
, p. 121 - 130 (2007/10/03)
A new strategy based on the use of diethylamine triazenes for stabilization and generation of polymer supported diazonium ions was described. New economical syntheses of four new polymeric supports with 3- and 6-carbon atom spacers and triazene linkers derived from meta- and para-aminophenol were described and compared to the traditional methods. The possible application of the polymer bound triazene masked diazonium salts as supports for immobilization of secondary amines (nortropine and 4-piperidinole and their esterification and oxidation), and as amine scavengers was shown. The new supports with meta-C3-T2 and para-C3-T2 linkers showed higher loadings and typically gave products with good yields and purities.
