118633-39-9

Upstream product

• 13495-32-4 Benzoyl-isobutyryl-peroxyd 
• 108-23-6 isopropyl chloroformate 
• 65-85-0 benzoic acid 

Downstream Products

• 57872-48-7 ketoprofen methyl ester 
• 422550-82-1 3-benzoyl-N-methoxy-N,5-dimethylbenzamide 
• 332133-57-0 4-benzoyl-2-methoxypyridine 
• 54885-02-8 phenyl(quinolin-6-yl)methanone 
• 643-65-2 3-methyl benzophenone 
• 32388-73-1 [3-(1-methylethyl)phenyl]phenylmethanone 
• 644-13-3 C₆H₅COC₁₀H₇ 
• 31766-07-1 (3-(dimethylamino)phenyl)(phenyl)methanone 
• 13319-70-5 3,5-dimethylbenzophenone 
• 1016-78-0 3-chlorobenzophenone 
• 6136-67-0 3-methoxybenzophenone 

Relevant academic research and scientific papers

Ortho C-H acylation of aryl iodides by palladium/norbornene catalysis

Reported herein is a palladium/norbornene-catalyzed ortho-arene acylation of aryl iodides by a Catellani-type C-H functionalization. This transformation is enabled by isopropyl carbonate anhydrides, which serve as both an acyl cation equivalent and a hydride source. Double (re)agent: A palladium/norbornene-catalyzed ortho-acylation of aryl iodides was developed, and is enabled by isopropyl carbonate anhydrides, which function as both an acyl cation equivalent and a hydride source. This reaction exhibits excellent functional-group compatibility and broad substrate scope. Heterocycle moieties can be tolerated on both the aryl and acyl partners. FG=functional group.