118644-10-3

Usage

General Description

2,5,8-Tri-tert-butyl-5,8-dihydro-2H-Benzo[1,2-c:3,4-c':5,6-c'']tripyrrole is a complex and highly stable organic compound. It is a synthetic molecule that belongs to the class of pyrrole-based compounds, which are known for their unique electronic and optical properties. The presence of three tert-butyl groups on the molecule provides steric hindrance and protects the core structure, making it resistant to oxidation and degradation. 2,5,8-Tri-tert-butyl-5,8-dihydro-2H-Benzo[1,2-c:3,4-c':5,6-c'']tripyrrole, has potential applications in materials science, particularly in the development of organic semiconductors, dyes, and sensors. Its unique structure and properties make it a subject of interest in the field of organic chemistry and materials research.

Upstream product

• 75-64-9 tert-butylamine 
• 119198-90-2 3-[3,5-Bis-(2,2-bis-ethoxycarbonyl-vinyl)-2,4,6-tris-bromomethyl-phenyl]-2-ethoxycarbonyl-acrylic acid ethyl ester 
• 3095-73-6 1,2,3,4,5,6-hexa(bromomethyl)benzene 
• 118644-11-4 2,5,8-Tri-tert-butyl-2,3,4,5,6,7,8,9-octahydro-2H-benzo<1,2-c:3,4-c':5,6-c>tripyrrol 
• 87-85-4 Hexamethylbenzene 
• 118644-12-5 2,5,8-Tri-tert-butyl-2,3,4,5,6,7,8,9-octahydro-2H-benzo<1,2-c:3,4-c':5,6-c>tripyrrol-2,5,8-trioxid 

Relevant academic research and scientific papers

Structure and Reactivity of Isoannellated Heterocyclic Systems with 4n?- and (4n+2)?-Electrons, XIV. Tri- and Tetracyclic Hetarenes with Localized or Delocalized Pyrrole Units

2,7-Di-tert-butyl-2,7-dihydro-benzodipyrrole (2b) and 2,5,8-Tri-tert-butyl-5,8-dihydro-2H-benzotripyrrole (3b) have been prepared by acetolysis of the corresponding tri- and tetracyclic N-oxides, isolated in crystallinic form and characterized by spectroscopic data.The scope of the N-oxide route is documented and the existence of benzo-annellated pyrroles is proofed.The stabilizing effect of the tert-butyl group is presumably supported by the vicinal annellated heterocycles. - Keywords: Benzo-annellated Di- and Tripyrroles, Synthesis, Isolation, Spectroscopic Properties, Cycloaddition reactions

A Retro-malonate Addition Reaction: Synthesis of 3,4-Condensed Heteroaromatic Pyrroles

Treatment of bromo alkylidenemalonates (1)-(4) with ammonia or amines afforded 3,4-condensed heteroaromatic pyrroles (5)-(8) in excellent yields; benzotripyrroles (19)-(21) were synthesized by the same method.