1188474-27-2

Basic information

• Product Name: (Z)-2-(chroman-4-ylidene)-1-phenylpropan-1-ol
• Synonyms: (Z)-2-(chroman-4-ylidene)-1-phenylpropan-1-ol
• CAS NO: 1188474-27-2
• Molecular Weight: 266.34
• Mol File: 1188474-27-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (Z)-2-(chroman-4-ylidene)-1-phenylpropan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-(chroman-4-ylidene)-1-phenylpropan-1-ol(1188474-27-2)
• EPA Substance Registry System: (Z)-2-(chroman-4-ylidene)-1-phenylpropan-1-ol(1188474-27-2)

Safety Data

• Hazardous Substances Data: 1188474-27-2(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 533-58-4 2-Iodophenol 
• 10229-10-4 pent-3-yn-1-ol 
• 1188474-17-0 1-(but-2-yn-1-yloxy)-2-iodobenzene 
• 1188474-18-1 1-iodo-2-(pent-3-yn-1-yloxy)benzene 

Downstream Products

• 1188474-28-3 (E)-4-(1-phenylprop-1-en-2-yl)-2H-chromene 

Relevant articles and documents

Nickel-Catalyzed Electrochemical Cyclization of Alkynyl Aryl Iodide and the Domino Reaction with Aldehydes

An intramolecular carbometallation of a triple bond promoted by electrochemistry and mediated by nickel catalysis is described. This domino process transforms various aryl halides bearing a propargyl chain into substituted heterocycles in one single operation, with high stereoselectivities and in good to high yields. This reaction, characterized by a cyclic voltammetry set of experiments, proceeds following a syn-exo-dig cyclization process. When run at 80 °C, vinylbenzofuranes that are suitable substrates for cycloaddition reactions are obtained.

Heterocyclization by catalytic carbonickelation of alkynes: A domino sequence involving vinylnickels

Reaction of Ni(0) in the presence of iodoarylethers 1 leads, after syn intramolecular carbonickelation of the triple bond, to nucleophilic vinylnickels which can be trapped, in a tandem process, by various electrophiles introduced at the onset of the reac