118878-05-0Relevant articles and documents
Hydroacylation of Simple Alkyl Vinyl Ketones Using Organotetracarbonylferrates
Yamashita, Masakazu,Tashika, Haruyoshi,Suemitsu, Rikisaku
, p. 691 - 692 (1989)
Alkyl vinyl ketones were hydroacylated by organotetracarbonylferrates to the corresponding 1,4-diketones in good yields in dipolar aprotic solvents such as dimethylacetamide.The addition of 18-Crown-6 made an increase of the yields.
Ruthenium-catalyzed three-component coupling via hydrative conjugate addition of alkynes to alkenes: One-pot synthesis of 1,4-dicarbonyl compounds
Chen, Yiyun,Park, Sung Hwan,Lee, Chung Whan,Lee, Chulbom
supporting information; experimental part, p. 2000 - 2004 (2011/11/07)
A catalytic three-way rendezvous: Terminal alkynes undergo metal vinylidene formation, anti-Markovnikov hydration to give a metal acyl complex, and conjugate addition to produce synthetically useful 1,4-dicarbonyl compounds under ruthenium catalysis. This one-pot three-component coupling reaction is a useful platform for further exploration in alkyne functionalization.