1189364-85-9

Basic information

• Product Name: 2,2′-[(1S,2S)-(+)-1,2-Cyclohexanediylbis[(E)-(nitriloMethylidyne)]]bis[4-(tert-butyl)-6-(4-MorpholinylMethyl)phenol]
• Synonyms: Phenol, 2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4-(1,1-dimethylethyl)-6-(4-morpholinylmethyl)-;6,6'-((1E,1'E)-((1S,2S)-Cyclohexane-1,2-diylbis(azanylylidene))bis(methanylylidene))bis(4-(tert-butyl)-2-(morpholinomethyl)phenol)
• CAS NO: 1189364-85-9
• Molecular Formula: C38H56N4O4
• Molecular Weight: 632.87564
• Mol File: 1189364-85-9.mol
• Article Data: 4

Chemical Properties

• Melting Point: 132-140°C
• Boiling Point: 729.1±60.0 °C(Predicted)
• Appearance: /
• Density: 1.16±0.1 g/cm3(Predicted)
• PKA: 13.05±0.40(Predicted)
• CAS DataBase Reference: 2,2′-[(1S,2S)-(+)-1,2-Cyclohexanediylbis[(E)-(nitriloMethylidyne)]]bis[4-(tert-butyl)-6-(4-MorpholinylMethyl)phenol](CAS DataBase Reference)
• NIST Chemistry Reference: 2,2′-[(1S,2S)-(+)-1,2-Cyclohexanediylbis[(E)-(nitriloMethylidyne)]]bis[4-(tert-butyl)-6-(4-MorpholinylMethyl)phenol](1189364-85-9)
• EPA Substance Registry System: 2,2′-[(1S,2S)-(+)-1,2-Cyclohexanediylbis[(E)-(nitriloMethylidyne)]]bis[4-(tert-butyl)-6-(4-MorpholinylMethyl)phenol](1189364-85-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 1189364-85-9(Hazardous Substances Data)

Usage

Molecular structure

2,2′-[(1S,2S)-(+)-1,2-Cyclohexanediylbis[(E)-(nitriloMethylidyne)]]bis[4-(tert-butyl)-6-(4-MorpholinylMethyl)phenol] consists of two cyclohexane rings connected by a bis(nitriloMethylidyne) group and two phenolic groups attached.

Substituents

The compound contains tert-butyl and morpholinylmethyl substituents on the phenolic rings, which contribute to its stability and reactivity.

Optical isomerism

The compound has (1S,2S)-(+) configuration, indicating the arrangement of the cyclohexane rings and their chirality.

Application as a stabilizer and antioxidant

It is commonly used in polymers, plastics, and other materials to prevent degradation caused by heat, light, or oxygen exposure.

Use in synthesis of organic compounds

The compound can be used as an intermediate or reagent in the synthesis of various organic compounds.

Chelating agent

It can act as a chelating agent in chemical processes, binding to metal ions and facilitating reactions.

Upstream product

• 1121-22-8 trans-1,2-Diaminocyclohexane 
• 252735-68-5 2-Hydroxy-3-(morpholin-4-ylmethyl)-5-tert-butylbenzaldehyde 
• 18811-63-7 N-(ethoxymethyl)morpholine 
• 23039-28-3 3-(tert-butyl)benzaldehyde 
• 98-54-4 para-tert-butylphenol 
• 2725-53-3 2-hydroxy-5-t-butylbenzaldehyde 
• 20439-47-8 (1R,2R)-1,2-diaminocyclohexane 

Relevant articles and documents

METHOD OF PREPARING POLY(ALKYLENE CARBONATE) VIA COPOLYMERIZATION OF CARBON DIOXIDE/EPOXIDE IN THE PRESENCE OF NOVEL COMPLEX

Provided is a method of preparing poly(alkylene carbonate) using a molecular weight regulator in a process of preparing a copolymer of carbon dioxide/epoxide using a novel complex synthesized from salen-type ligand including a quaternary ammonium salt as a catalyst. According to the present invention, even though the molecular weight regulator is used, an activity of the catalyst may be stably maintained, whereby the low molecular weight of poly(alkylene carbonate) having a desirable level may be effectively provided. In addition, it is expected that since the novel complex as the catalyst of the present invention has a simple structure as compared to the existing copolymerization catalyst, due to the economical preparation cost thereof, the novel complex may be effectively applied to a large-scale commercial process.

Salen-derived catalysts containing secondary basic groups in the addition of diethylzinc to aldehydes

matrix presented A set of modular bifunctional salen catalysts which contain Lewis acid and Lewis base activating groups is described. These groups can be altered independently to control nucleophilic and electrophilic activation of the reacting substrates. These salen-derived catalysts show enhanced reactivity in the addition of diethylzinc to aldehydes with respect to most other salen, amino alcohol, and diamine derived catalysts and reactivity comparable to that of Ti complexes of bis-sulfonamides and diols.