118947-88-9Relevant articles and documents
CYCLIZATION REACTIONS OF NITRILS. 29. REGIOSELECTIVE SYNTHESIS OF 6-ARYL-3-CYANO-2(1H)-PYRIDINETHIONES AND THE CORRESPONDING SELENONES AND THEIR CHARACTERISTICS
Rodinovskaya, L.A.,Sharanin, Yu.A.,Shestopalov, A.M.,Litvinov, V.P.
, p. 658 - 664 (2007/10/02)
The condensation of cyanothio- and cyanoselenoacetamide with 3-aryl-3-oxo-1-piperidino-1-propene or sodium 3-aryl-3-oxo-1-propen-1-olate takes place regioselectively with the formation of the 6-aryl-3-cyano-2(1H)-pyridinethiones or the corresponding selenones.Thienopyridines, thiazolopyridinium salts, and other annellated heterocycles were obtained from the 6-aryl-3-cyano-2(1H)-pyridinethiones.