1190207-30-7Relevant articles and documents
Steric tuning of the amidomonophosphane-rhodium(l) catalyst in asymmetric addition of arylboroxines to n-phosphinoyl aldimines
Hao, Xinyu,Kuriyama, Masami,Chen, Qian,Yamamoto, Yasutomo,Yamada, Ken-Ichi,Tomioka, Kiyoshi
, p. 4470 - 4473 (2009)
Highly enantioselective rhodium-catalyzed addition of arylboroxlnes to N-phosphinoylaldimines was realized by the steric tuning of a dlphenylphosphorus moiety to a di(o-tolyl)phosphorus moiety of a chiral amidomonophosphane. The presence of MS 4 A in a 5:1 solvent mixture of dioxane-propanol was essential to afford the corresponding dlarylmethylamines In high yield.