1190211-36-9Relevant academic research and scientific papers
Scope and limitations of samarium diiodide induced cyclizations of alkenyl-substituted γ-keto esters to benzannulated cyclooctanol derivatives
Saadi, Jakub,Reissig, Hans-Ulrich
, p. 2089 - 2092 (2009)
A series of γ-keto esters bearing various alkenyl substituents were synthesized and subjected to samarium diiodide mediated 8-endo-trig ketyl-alkene coupling reactions. Highly substituted benzannulated cyclooctanol derivatives were obtained in good yields
Highly substituted benzannulated cyclooctanol derivatives by samarium diiodide-induced cyclizations
Saadi, Jakub,Bruedgam, Irene,Reissig, Hans-Ulrich
supporting information; experimental part, p. 1229 - 1245 (2011/03/22)
A series of γ-oxo esters suitably substituted with various styrene subunits was subjected to samarium diiodide-induced 8-endo-trig cyclizations. Efficacy, regioselectivity and stereoselectivity of these reactions via samarium ketyls strongly depend on the
