119079-16-2Relevant academic research and scientific papers
Air-induced anti-Markovnikov addition of secondary phosphine oxides and H-phosphinates to alkenes
Hirai, Takayoshi,Han, Li-Biao
, p. 53 - 55 (2007)
(Chemical Equation Presented) Air (oxygen) induces the addition of secondary phosphine oxides and H-phosphinates to alkenes to selectively produce the corresponding anti-Markovnikov adducts in good to high yields. Mechanistic studies show that the addition probably proceeds via a radical chain mechanism.
Copper-catalyzed allylic C-H phosphonation
Yang, Bin,Zhang, Hong-Yu,Yang, Shang-Dong
supporting information, p. 3561 - 3565 (2015/03/30)
An efficient copper-catalyzed allylic C-H phosphonation reaction has been developed under mild reaction conditions. This method exhibits high regioselectivity and stereoselectivity. Various alkenes with useful functional groups are compatible in this tran
