109730-18-9Relevant academic research and scientific papers
Rapid and Efficient Microwave-Assisted Hydrophosphinylation of Unactivated Alkenes with H -Phosphinic Acids without Added Metal or Radical Initiator
Troupa, Panagiota,Katsiouleri, Georgia,Vassiliou, Stamatia
supporting information, p. 2714 - 2719 (2015/11/27)
A microwave-assisted hydrophosphinylation of unactivated alkenes with phosphinic acid and its derivatives under metal-free and initiator-free conditions is reported. Such hydrophosphinylations are operationally simple, use aqueous hypophosphorus acid, H-phenylphosphinic acid, and H-alkylphosphinic acids, and seem to proceed by a radical mechanism. Good isolated yields were obtained using a reasonable excess of the appropriate reagent.
Synthesis of disubstituted phosphinates via palladium-catalyzed hydrophosphinylation of H-phosphinic acids
Petit, Christelle,Fecourt, Fabien,Montchamp, Jean-Luc
supporting information; experimental part, p. 1883 - 1888 (2011/10/04)
The first metal-catalyzed hydrophosphinylation of unsaturated hydrocarbons with H-phosphinic acids is described. A strategy to activate the P-H bond through control of the tautomeric equilibrium using ethylene glycol is described. The reactions also avoid chromatographic purification. Copyright
