Cas 119093-14-0,3'-O-acetylthymmidin-5'-yl 5'-O-(9-phenylxanthen-9-yl)thymidin-3'-yl phosphorofluoridate

119093-14-0

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Basic information

Product Name: 3'-O-acetylthymmidin-5'-yl 5'-O-(9-phenylxanthen-9-yl)thymidin-3'-yl phosphorofluoridate
Synonyms: 3'-O-acetylthymmidin-5'-yl 5'-O-(9-phenylxanthen-9-yl)thymidin-3'-yl phosphorofluoridate
CAS NO:119093-14-0
Molecular Formula:
Molecular Weight: 846.76
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: 3'-O-acetylthymmidin-5'-yl 5'-O-(9-phenylxanthen-9-yl)thymidin-3'-yl phosphorofluoridate(CAS DataBase Reference)
NIST Chemistry Reference: 3'-O-acetylthymmidin-5'-yl 5'-O-(9-phenylxanthen-9-yl)thymidin-3'-yl phosphorofluoridate(119093-14-0)
EPA Substance Registry System: 3'-O-acetylthymmidin-5'-yl 5'-O-(9-phenylxanthen-9-yl)thymidin-3'-yl phosphorofluoridate(119093-14-0)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 119093-14-0(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 119093-14-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,9,0,9 and 3 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 119093-14:
(8*1)+(7*1)+(6*9)+(5*0)+(4*9)+(3*3)+(2*1)+(1*4)=120
120 % 10 = 0
So 119093-14-0 is a valid CAS Registry Number.

119093-14-0Upstream product

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119093-14-0Relevant academic research and scientific papers

New General Synthesis of Organophosphorus P-F Compounds via Reaction of Azolides of Phosphorus Acids with Acyl Fluorides: Novel Route to 2-Deoxynucleosidyl Phosphorofluoridates and Phosphorodifluoridates

Dabkowski, Wojciech,Michalski, Jan,Wasiak, Jacek,Cramer, Friedrich

, p. 817 - 820 (2007/10/02)

Tetra- and tri-coordinate P-N-imidazole derivatives and their structural analogous react smoothly with acyl fluorides to give the corresponding P-F compounds an almost quantitative yield.This method has been successfully applied to produce 2-deoxynucleosidyl phosphorofluoridates and phosphorodifluoridates.

Fluorination of Trimethylsilyl Phosphites and their Structural Analogues by Sulfuryl Chloride Fluoride: Simple Preparation of Phosphorofluoridates and Related Compounds, including Deoxynucleoside Phosphorofluoridates

Dabkowski, Wojciech,Cramer, Friedrich,Michalski, Jan

, p. 1447 - 1452 (2007/10/02)

Trimethylsilyl esters of general formula RR'POSiMe3 react in a quantitative and fully chemoselective way with sulfuryl chloride fluoride, ClSO2F, under extremely mild conditions to give phosphorofluoridates RO(R'O)P(O)F of high purity.This work provides easy access to all type of fluoridates from non-toxic starting materials.The synthetic usefulness of this method is illustrated by the synthesis of 3'- and 5'-mononucleoside phosphorofluoridates 10 and 3',5'-dinucleoside phosphorofluoridates 11 from the corresponding nucleoside trimethylsilyl phosphites.

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