119125-13-2

Basic information

• Product Name: methyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2-C-p-tolylsulfonyl-α-D-glucopyranoside
• CAS NO: 119125-13-2
• Molecular Weight: 434.51
• Mol File: 119125-13-2.mol

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2-C-p-tolylsulfonyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2-C-p-tolylsulfonyl-α-D-glucopyranoside(119125-13-2)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2-C-p-tolylsulfonyl-α-D-glucopyranoside(119125-13-2)

Safety Data

• Hazardous Substances Data: 119125-13-2(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 111549-50-9 methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-p-tolylsulfonyl-α-D-erythro-hex-2-enopyranoside 

Relevant articles and documents

REACTIONS OF METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-2-C-p-TOLYLSULFONYL-α-D-erythro-HEX-2-ENOPYRANOSIDE AND ITS PHENYL ANALOGUE WITH SODIUM METHOXIDE

Reaction of the title methyl glycoside 5 with methanolic sodium methoxide afforded mainly the isomeric α-D-erythro-hex-3-enopyranoside derivative 13, formed by migration of the double bond from C-2 to C-3, together with 1,5-anhydro-4,6-O-benzylidene-2-deo