REACTIONS OF METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-2-C-p-TOLYLSULFONYL-α-D-erythro-HEX-2-ENOPYRANOSIDE AND ITS PHENYL ANALOGUE WITH SODIUM METHOXIDE

DOI: 10.1016/0008-6215(88)84111-9

Source and publish data:

Carbohydrate Research p. 77 - 86 (1988)

Update date:2022-08-03

Topics:

Authors:

Sakakibara, Tohru

Yamamoto, Azuma

Ishido, Yoshiharu

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Article abstract of DOI:10.1016/0008-6215(88)84111-9

Reaction of the title methyl glycoside 5 with methanolic sodium methoxide afforded mainly the isomeric α-D-erythro-hex-3-enopyranoside derivative 13, formed by migration of the double bond from C-2 to C-3, together with 1,5-anhydro-4,6-O-benzylidene-2-deo

Full text of DOI:10.1016/0008-6215(88)84111-9

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