1192352-41-2

Upstream product

• 10025-99-7 potassium tetrachloroplatinate(II) 
• 75-09-2 dichloromethane 
• 131276-25-0 1,8-bis-(diphenylphosphino)anthracene 

Downstream Products

• 1192352-38-7 [PtI(1,8-bis(diphenylphosphino)anthracene^(1-))]*CH₂Cl₂ 
• 1192352-54-7 Pt₂Cl₂((C₁₄H₆O₂(P(C₆H₅)2)2)2O) 
• 1192352-47-8 PtCl(C₁₄H₆O(OH)(P(C₆H₅)2)2)*CH₃CN 

Relevant academic research and scientific papers

Photooxidation of a platinum-anthracene pincer complex: formation and structures of pt"-anthrone and -ketal complexes

Irradiating the cyclometalated pincer complex PtII(DPA)Cl (1, DPA = 1, 8-bis(dlphenylphosphlno)anthracene) In the presence of O2 led to three sequential oxidations of the anthracenyl ring. The first photoproduct, a PtII-9, 10-endoperoxide complex, was converted photochemically to a PtII-9-hydroxyanthrone complex A which was further oxygenated to a PtII-hemlketal (B). The oxidation of A, which could be accelerated by light irradiation, probably Involved a Pt II-anthraqulnone Intermediate. B underwent acid-catalyzed ketalizatlon to form a binuclear Pt2II-diketal (B1). The photolysis was followed by UV-vls absorption and NMR spectroscopy, and the structures of A and B1 were characterized by single crystal X-ray diffraction.