119288-90-3Relevant academic research and scientific papers
Palladium-Catalyzed Silylation of Aryl Bromides Leading to Functionalized Aryldimethylsilanols
Denmark, Scott E.,Kallemeyn, Jeffrey M.
, p. 3483 - 3486 (2007/10/03)
Equation presented. A mild and general palladium-catalyzed insertion of 1,2-diethoxy-1,1,2,2-tetramethyldisilane into a variety of aryl bromides affords the aryldimethylsilyl ethers in high yields. Hydrolysis of the ethers under pH-optimized conditions results in the exclusive formation of the desired aryldimethylsilanols.
Beitraege zur Chemie der Silicium-Stickstoffverbindungen. CLXIV. 1-Silaisoindolinone: Strukturanaloga des Saccharins, und verwandte Verbindungen
Wannagat, Ulrich,Schrader, Rolf
, p. 95 - 108 (2007/10/02)
2-(Chlorodimethylsilyl)benzoyl chloride, prepared in high yield from 2-(4-methoxyphenyldimethylsilyl)benzoic acid and thionyl chloride or phosphorus pentachloride, was investigated in its reactions with amines and alcohols. 1,1-Dimethyl-1-sila-isoindolin-
