119294-21-2Relevant academic research and scientific papers
SYNTHESIS AND PROPERTIES OF sym-TRIAZENE DERIVATIVES 12. SYNTHESIS OF 2,4-BIS(TRICHLOROMETHYL)-6-SUBSTITUTED sym-TRIAZENES CONTAINING A STERICALLY HINDERED PHENOL GROUP
Kelarev, V. I.,Koshelev, V. N.,Belov, N. V.,Malova, O. V.,Karakhanov, R. A.
, p. 218 - 221 (2007/10/02)
6-Substituted 2,4-bis(trichloromethyl)-sym-triazenes containing the 2,6-di-tert-butylphenol group are synthesized by simultaneous cyclotrimerization of trichloroacetonitrile with the nitrile or thiocyanate derivative of the sterically hindered phenol in the presence of gaseous HCl.Significant amounts of 2,4,6-tris(trichloromethyl)-sym-triazene are formed as a by-product.
