29027-77-8

Upstream product

• 128-39-2 2,6-di-tert-butylphenol 
• 107-13-1 acrylonitrile 
• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 
• 75-05-8 acetonitrile 

Downstream Products

• 20170-32-5 4-hydroxy-3,5-di-tert-butylphenylpropionic acid 
• 84654-57-9 β-[3,5-di(tert-butyl)-4-hydroxyphenyl]propionic acid ethyl imino ester hydrochloride 
• 136415-08-2 2-methoxyethyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionimidate hydrochloride 
• 114811-81-3 2-amino-4-trichloromethyl-6-<β-(4-hydroxy-3,5-di-tert-butylphenyl)ethyl>-sym-triazine 
• 114811-82-4 4-[2-(4-Amino-6-phenyl-[1,3,5]triazin-2-yl)-ethyl]-2,6-di-tert-butyl-phenol 
• 114811-84-6 2-amino-4,6-bis<β-(4-hydroxy-3,5-di-tert-butylphenyl)ethyl>-sym-triazine 
• 6542-67-2 2,4,6-tris(trichloromethyl)-s-triazine 
• 119294-21-2 2,4-bis(trichloromethyl)-6-<β-(4-hydroxy-3,5-di-tert-butylphenyl)ethyl>-sym-triazine 
• 69217-41-0 3-(3,5-Di-tert-butyl-1-hydroxy-4-oxo-cyclohexa-2,5-dienyl)-propionitrile 
• 69217-43-2 Acetic acid 3,5-di-tert-butyl-1-(2-cyano-ethyl)-4-oxo-cyclohexa-2,5-dienyl ester 
• 13917-37-8 3,5-di-tert-butyl-4-hydroxyphenylpropionic acid 
• 114811-90-4 4-[2-(4-Amino-6-diethylamino-[1,3,5]triazin-2-yl)-ethyl]-2,6-di-tert-butyl-phenol 
• 114825-95-5 4-[2-(4-Amino-6-dimethylamino-[1,3,5]triazin-2-yl)-ethyl]-2,6-di-tert-butyl-phenol 
• 119294-31-4 C₅₃H₈₁N₅O₃ 

Relevant academic research and scientific papers

Transition Metal-Free Cross-Dehydrogenative Coupling Reaction of Coumarins with Acetonitrile or Acetone

A transition metal-free cross-dehydrogenative coupling of coumarins with acetonitrile or acetone has been established. A series of coumarins were subjected to reaction with acetonitrile or acetone in the presence of tert-butyl benzoperoxoate and potassium fluoride for direct synthesis of 3-cyanomethyl (or acetomethyl) coumarins. The method exhibits good functional group tolerance, and desired products were obtained in moderate to good yields. Meanwhile, a radical pathway was proposed to describe the cross-dehydrogenative coupling of coumarins with acetonitrile.

Cyanomethylative cyclization of unactivated alkenes with nitriles for the synthesis of cyano-containing ring-fused quinazolin-4(3H)-ones

The synthesis of cyano-containing ring-fused quinazolin-4(3H)-one derivatives was developed under metal-free conditions. This synthesis involves radical C(sp3)-H functionalization of alkyl nitriles, and cascade radical addition/cyclization with N-alkylated quinazolinones to deliver cyanoalkylated pyrrolo- and piperidino-quinazolin-4(3H)-ones in moderate to excellent yields. Moreover, a derivative of the natural product leucomidine C was synthesized conveniently using the current protocol.

Radical Chain Addition of Aryloxyl Radicals to Electron-deficient Alkeanes

Michael addition of aryloxyl radicals to electron-deficient alkenes in the presence of Ag+ is described.

SYNTHESIS AND PROPERTIES OF symm-TRIAZINE DERIVATIVES. 4.* SYNTHESIS OF 2,4,6-TRISUBSTITUTED symm-TRIAZINES CONTAINING STERICALLY-HINDERED PHENOL FRAGMENTS

2,4,6-Trisubstituted symm-triazines containing sterically-hindered phenol fragments were synthesized by the cyclotrimerization of ethyl iminoesters. 2,4,6-Trimercapto-symm-triazine derivatives containing shielded phenol residues may be formed by the cyclo