119342-90-4Relevant academic research and scientific papers
Synthetic utility of HCFC-123 (2,2-dichloro-1,1,1-trifluoroethane): the reaction between HCFC-123 and aldehydes using zinc
Tamura, Masanori,Sekiya, Akira
, p. 119 - 122 (1995)
HCFC-123 (2,2-dichloro-1,1,1-trifluoroethane) reacted with zinc and aldehydes to afford predominantly either 1-substituted 2-chloro-3,3-difluoro-2-propen-1-ols or 1-substituted 2,2-dichloro-3,3,3-trifluoro-1-propanols.The reactions proceeded via 1,1-dichloro-2,2,2-trifluoroethylzinc chloride as an organozinc intermediate. - Keywords: 2,2-Dichloro-1,1,1-trifluoroethane; Reaction; Aldehydes; Zinc; 1,1-Dichloro-2,2,2-trifluoroethylzinc chloride
Nucleophilic introduction of fluorinated alkyl groups into aldehydes and ketones using the corresponding alkyl halide with samarium(II) iodide
Yoshida, Masato,Suzuki, Daiki,Iyoda, Masahiko
, p. 643 - 648 (2007/10/03)
Fluorinated alkyl groups such as PhCF2, C6F13, CF3CCl2 and CF2CO2Et are nucleophilically introduced into an aldehyde or ketone using fluorinated alkyl halides with SmI2/sub
Radical Cyclization of Trifluoromethyl-substituted Carbon: A Facile Preparation of Trifluoromethylated Five-membered Ring Compounds
Watanabe, Yoshihiko,Yokozawa, Tsutomo,Takata, Toshikazu,Endo, Takeshi
, p. 431 - 434 (2007/10/02)
α-Trifluoromethyl carbon radicals, generated by the tributyltin radical, added intramolecularly to oleginic double bonds to afford the trifluoromethyl-substituted five-membered ring compounds.
