Synthetic utility of HCFC-123 (2,2-dichloro-1,1,1-trifluoroethane): the reaction between HCFC-123 and aldehydes using zinc

DOI: 10.1016/0022-1139(94)03141-L

Source and publish data:

Journal of Fluorine Chemistry p. 119 - 122 (1995)

Update date:2022-07-30

Topics:

Authors:

Tamura, Masanori

Sekiya, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-1139(94)03141-L

HCFC-123 (2,2-dichloro-1,1,1-trifluoroethane) reacted with zinc and aldehydes to afford predominantly either 1-substituted 2-chloro-3,3-difluoro-2-propen-1-ols or 1-substituted 2,2-dichloro-3,3,3-trifluoro-1-propanols.The reactions proceeded via 1,1-dichloro-2,2,2-trifluoroethylzinc chloride as an organozinc intermediate. - Keywords: 2,2-Dichloro-1,1,1-trifluoroethane; Reaction; Aldehydes; Zinc; 1,1-Dichloro-2,2,2-trifluoroethylzinc chloride

Full text of DOI:10.1016/0022-1139(94)03141-L

Products guided by the article

Product name:Benzenepropanol, a-(1,1-dichloro-2,2,2-trifluoroethyl)-

Cas No:119342-90-4

R&D Labs maybe for 119342-90-4

Shanghai Massive Chemical Technology Co., Ltd.

website:http://www.massivechem.com/

Contact:+86 21 34943721

Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Suzhou BEC Fine Chemicals Co., Ltd.

website:http://www.bek.com.cn

Contact:0512-68095917　 18913193865

Address:6, Jin Shan Road, Suzhou New District, 215011 China Suzhou Nations Pharmaceutical Innovation Center Inside
ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang

Relevant to this article

STEREOSPECIFIC DESULFINYLATION OF SULFINYLAZIRIDINES WITH ETHYLMAGNESIUM BROMIDE: A NOVEL SYNTHESIS OF (Z)-N-ARYLAZIRIDINES

Doi:10.1016/S0040-4039(00)80425-6
(1988)
Synthesis and reactivity of dialkyl lutetium complexes supported by a novel bis(phosphinimine)carbazole pincer ligand

Doi:10.1021/om900731x
(2009)
Alkylation of phenol by β-pinene in the presence of aluminum phenolate

Doi:10.1007/s10600-012-0154-z
(2012)
Regioselective Construction of α,α-Disubstituted Allylic Amines by the Ruthenium-Catalyzed Allylic Amination of Tertiary Allylic Acetates

Doi:10.1021/acs.orglett.6b03672
(2017)
New thiazoline-oxazoline ligands and their application in the asymmetric friedel-crafts reaction

Doi:10.1002/ejoc.200900683
(2009)
Transition metal complexes of a bis(carbene) ligand featuring 1,2,4-triazolin-5-ylidene donors: structural diversity and catalytic applications

Doi:10.1039/d0dt02142c
(2020)

Article Doi