145745-81-9

Basic information

• Product Name: (E)-methyl 2-<<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>(formyl)ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate
• CAS NO: 145745-81-9
• Molecular Weight: 498.737
• Mol File: 145745-81-9.mol

Chemical Properties

• CAS DataBase Reference: (E)-methyl 2-<<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>(formyl)ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl 2-<<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>(formyl)ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate(145745-81-9)
• EPA Substance Registry System: (E)-methyl 2-<<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>(formyl)ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate(145745-81-9)

Safety Data

• Hazardous Substances Data: 145745-81-9(Hazardous Substances Data)

Upstream product

• 145746-09-4 (E)-methyl 2-<1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-hydroxyethoxymethyl>-3-dimethyl(phenyl)silyl-2-enoate 
• 56169-20-1 2-(2,2-dimethoxyethyl)1,3-dithiane 
• 145745-77-3 (Z)-methyl 2-bromomethyl-3-dimethyl(phenyl)silylprop-2-enoate 
• 145745-78-4 2-tert-butyldimethylsiloxy-1-<2'-(2'',2''-dimethoxyethyl)-1',3'-dithian-2'-yl>ethanol 
• 138175-71-0 (E)-methyl 2-<2'-tert-butyldimethylsiloxy-1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate 
• 145745-76-2 (E)-2-Diethoxymethyl-3-(dimethyl-phenyl-silanyl)-prop-2-en-1-ol 
• 145746-07-2 (E)-methyl 3-dimethyl(phenyl)silyl-2-hydroxymethylprop-2-enoate 
• 119481-06-0 (E)-2-hydroxymethyl-2-[(dimethylphenylsilyl)methylene]ethanal 
• 145745-75-1 (Z)-methyl 2-diethoxymethyl-3-dimethyl(phenyl)silylprop-2-enoate 

Downstream Products

• 138175-72-1 (E)-methyl 2-<1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-<(E)-2''''-oxotetrahydrofuran-3-ylidene>ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate 
• 138175-87-8 (E)-methyl 2-<1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-<(Z)-2''''-oxotetrahydrofuran-3-ylidene>ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate 
• 145746-20-9 (2E)-Methyl 2-<(E)-1'-<2-(2''',2'''-Dimethoxyethyl)-1,3-dithian-2-yl>-4'-oxopent-2-enyloxymethyl>-3-propenoate 
• 145746-30-1 (1R^*,3aR^*,4R^*,7a^R*)-Methyl 6-(tert-Butyldimethylsiloxy)-1-<2'-(2'',2''-dimethoxyethyl)-1',3'-dithian-2'-yl>-4--1,4,5,7a-tetrahydro-3H-isobenzofuran-3a-carboxylate 
• 145746-30-1 (1R^*,3aS^*,4S^*,7a^R*)-Methyl 6-(tert-Butyldimethylsiloxy)-1-<2'-(2'',2''-dimethoxyethyl)-1',3'-dithian-2'-yl>-4--1,4,5,7a-tetrahydro-3H-isobenzofuran-3a-carboxylate 
• 138175-73-2 (1R*,3aS*,4S*,8bR*)-methyl 1-<2'-(2'',2''-dimethoxyethyl)-1',3'-dithian-2'-yl>-4-dimethyl(phenyl)silyl-1,4,5,7,8,8b-hexahydro-3H-benzo<1,2-b:3,4-c'>difuran-3a-carboxylate 
• 138175-73-2 (1R*,3aR*,4R*,*8bR*)-methyl 1-<2'-(2'',2''-dimethoxyethyl)-1',3'-dithian-2'-yl>-4-dimethyl(phenyl)silyl-1,4,5,7,8,8b-hexahydro-3H-benzo<1,2-b:3,4-c'>difuran-3a-carboxylate 
• 145746-36-7 (1R^*,3aS^*,4S^*,7a^R*)-Methyl 4-Dimethyl(phenyl)silyl-1-<2'-(formylmethyl)-1',3'-dithian-2'-yl>-6-oxoperhydroisobenzofuran-3a-carboxylate 
• 145746-12-9 (2E)-Methyl 2-<(E)-4'-tert-Butyldimethylsiloxy-1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>penta-2',4'-dienyloxymethyl>-3-propenoate 

Relevant articles and documents

Chemistry of Insect Antifeedants from Azadirachta indica (Part 12): Use of Silicon as a Control Element in the Synthesis of a Highly Functionalized Decalin Fragment of Azadirachtin

A diastereoselective synthesis of a highly functionalized decalin fragment 61 of the insect antifeedant azadirachtin 1 is described.An intramolecular Diels-Alder reaction of triene 15 and subsequent intramolecular aldol reaction were employed to assemble