119594-92-2Relevant articles and documents
Palladium Assisted Transfer Hydrogenation of Cyclic α,β-Unsaturated Ketones by Ammonium Formate
Rao, H. Surya Prakash,Reddy, K. Subba
, p. 171 - 174 (1994)
α,β-Unsaturated ketones can be hydrogenated conveniently under catalytic hydrogenation conditions using ammonium formate / Pd-C (10percent) in refluxing methanol.
Improved dienophilicity of nitrocycloalkenes: Prospects for the development of a trans-Diels-Alder paradigm
Woo, Han Kim,Jun, Hee Lee,Danishefsky, Samuel J.
, p. 12576 - 12578 (2009)
(Chemical Equation Presented) The development of an efficient and stereoselective trans-Diels-Alder paradigm is described. A central element of this transformation is the introduction of a temporary dienophilic functionality (A), which serves both to acti
Enzymes in Organic Synthesis. 46. Regiospecific and Stereoselective Horse Liver Alcohol Dehydrogenase Catalyzed Reductions of cis- and trans-Bicyclononanones
Krawczyk, Andrzej R.,Jones, J. Bryan
, p. 1795 - 1801 (2007/10/02)
Further evidence for the preference of horse liver alcohol dehydrogenase for six-membered rather than five-membered ring ketone substrates is presented.This chemospecificity can be exploited preparatively, as illustrated by the HLADH-catalyzed reductions