119690-91-4

Basic information

• Product Name: 4-hydroxy-N-phenylhexanamide
• Synonyms: 4-hydroxy-N-phenylhexanamide
• CAS NO: 119690-91-4
• Molecular Weight: 207.272
• Mol File: 119690-91-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-hydroxy-N-phenylhexanamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-hydroxy-N-phenylhexanamide(119690-91-4)
• EPA Substance Registry System: 4-hydroxy-N-phenylhexanamide(119690-91-4)

Safety Data

• Hazardous Substances Data: 119690-91-4(Hazardous Substances Data)

Upstream product

• 859189-41-6 N-phenylhex-3-enamide 
• 98857-99-9 (E)-3-hexenoic acid phenyl amide 
• 98857-98-8 (Z)-3-hexenoic acid phenyl amide 
• 106-88-7 ethyloxirane 
• 103-84-4 Acetanilid 

Downstream Products

• 119691-01-9 5-Ethyl-1-(4-methoxy-phenyl)-pyrrolidin-2-one 
• 10312-40-0 5-ethyl-2-pyrrolidinone 
• 119702-17-9 5-ethyl-1-phenylpyrrolidin-2-one 

Relevant articles and documents

Iridium-Catalyzed Distal Hydroboration of Aliphatic Internal Alkenes

The regioselective hydroboration of aliphatic internal alkenes remains a great challenge. Reported herein is an iridium-catalyzed hydroboration of aliphatic internal alkenes, providing distal-borylated products in good to excellent yields with high regioselectivity (up to 99:1). We also demonstrate that the C?B bond of the distal-borylated product can be readily converted into other functional groups. DFT calculations indicate that the reaction proceeds through an unexpected IrIII/IrV cycle.

REACTION OF OXIRANES WITH DIANIONS OF SECONDARY AMINES. NEW ENTRY TO 5-ALKYLSUBSTITUTED γ-LACTAMS

The oxirane ring cleavage with dilithiated secondary amides was accelerated by the addition of boron trifluoride-etherate to afford γ-hydroxyamides, which were transformed into 5-alkylsubstituted γ-lactams via an intramolecular N-alkylation reaction.