119867-11-7

Basic information

• Product Name: (3-cyclohexenyl)-iodomethane
• Synonyms: (3-cyclohexenyl)-iodomethane
• CAS NO: 119867-11-7
• Molecular Weight: 222.069
• Mol File: 119867-11-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3-cyclohexenyl)-iodomethane(CAS DataBase Reference)
• NIST Chemistry Reference: (3-cyclohexenyl)-iodomethane(119867-11-7)
• EPA Substance Registry System: (3-cyclohexenyl)-iodomethane(119867-11-7)

Safety Data

• Hazardous Substances Data: 119867-11-7(Hazardous Substances Data)

Upstream product

• 72581-32-9 cyclohex-3-enylmethanol 
• 92864-78-3 cyclohex-3-en-1-ylmethyl 4-methylbenzenesulfonate 

Downstream Products

• 126497-20-9 ethyl 3-(3-cyclohexenyl)-2,2-dichloropropanoate 
• 1352812-27-1 C₁₁H₁₈O₂ 
• 115141-15-6 3-(3-cyclohexenyl)-2,2-dichloropropanamide 
• 115119-93-2 3-(3-cyclohexenyl)-2,2-dichloropropionitrile 
• 389607-96-9 3-(cyclohex-3-en-1-yl)-1-phenyl-1-propanone 
• 119867-29-7 diethyl 3-(3-cyclohexenyl)-2-methylpropanoate-2-carboxylate 
• 119867-22-0 methyl 2-chloro-3-(3-cyclohexenyl)-2-methylpropanoate 
• 119867-32-2 2-chloro-3-(3-cyclohexenyl)-2-methylpropanoic acid 
• 119867-21-9 3-(3-cyclohexenyl)-2-methylpropanoic acid 
• 389607-95-8 3-(3-cyclohexenyl)-propiophenone N,N-dimethylhydrazone 

Relevant articles and documents

Stereo- and regioselectivity of cyclization reactions in conformationally restricted epoxy ketones: Evaluation of C- versus O-alkylation process

The intramolecular addition reaction of metal enolates of ketones to oxiranes has been applied to a series of epoxy ketones derived from cyclohexene oxide. γ-Hydroxy ketones (γ-HKs, C-alkylation products) or hydroxy enol ethers (HEEs, O-alkylation products) are obtained, depending on the nature of the cyclic transition state in each case involved and the application of the Fu?rst-Plattner rule. The formation of HEEs by reaction of the same epoxy ketones under acid conditions is also described. In some cases, regioconvergent or chemoselective processes are conveniently obtained.