119873-75-5Relevant academic research and scientific papers
A general synthesis of vinylic silyl hydrides using nickel catalysis. Applications to the syntheses of silylene-tethered conjugated polymers
Chen, Ruey-Min,Luh, Tien-Yau
, p. 1197 - 1206 (2007/10/03)
Treatment of benzylic or allylic dithioacetals with Me2((i)PrO)SiCH2MgCl in the presence of NiCl2(PPh3)2 catalyst yielded the corresponding i-propoxy(vinyl)silanes which are reduced with LiAlH4/
Enantioselective Synthesis of Epoxides: Sharpless Epoxidation of Alkenysilanols
Chan, T. H.,Chen, L. M.,Wang, D.
, p. 1280 - 1281 (2007/10/02)
Sharpless epoxidation of the alkenylsilanol (6) followed by protodesilylation gave styrene oxide with high enentiomeric excess.
