1198757-08-2Relevant academic research and scientific papers
Cerium(iii) complexes with azolyl-substituted thiophenolate ligands: Synthesis, structure and red luminescence
Ilichev, Vasily A.,Silantyeva, Liubov I.,Grishin, Ivan D.,Rozhkov, Anton V.,Rumyantcev, Roman V.,Fukin, Georgy K.,Bochkarev, Mikhail N.
, p. 24110 - 24116 (2019)
In order to obtain molecular Ce(iii) complexes which emit red light by f-d transitions the azolyl-substituted thiophenolates were used as the ligands. The thiophenolate Ce(iii) complexes were synthesized by the reaction of Ce[N(SiMe3)2/su
Synthesis, characterization, and antimicrobial activity of palladium(II) and platinum(II) complexes with 2-substituted benzoxazole ligands
Samota, Mahesh Kumar,Seth, Gita
, p. 44 - 50 (2010)
The synthesis and antimicrobial activity of palladium(II) and platinum(II) complexes derived from heterocyclic bidentate ligands, namely 2-(2′-aminophenyl)benzoxazole [L1H2], 2-(2′-hydroxyphenyl)benzoxazole [L2H], and 2-(2′- mercaptophenyl)benzoxazole [L3H], are reported here. These complexes have been characterized by elemental analyses, molecular weight determinations, conductance measurements, infrared, 1H NMR, and electronic spectral studies. The resulting colored complexes are monomeric in nature. On the basis of above-described studies, square-planar geometry has been suggested for the resulting complexes. The ligands and their metal complexes were tested against certain microorganisms to assess their antimicrobial properties. The results indicate that the metal complexes are found more active than the parent ligands.
Synthesis, characterization, and biological activity of organophosphates derived from substituted benzoxazole
Samota, Mahesh Kumar,Jhajharia, Priyanka,Seth, Gita
experimental part, p. 309 - 315 (2010/01/18)
The reaction of phosphorus oxychloride/phosphorus thiochloride with 2-(2'-mercaptophenyl)benzoxazole in 1:1, 1:2, and 1:3 molar ratio in the presence of stoichiometric amounts of triethylamine has afforded a series of organophosphates. These organophospha
A one-pot, two-step microwave-assisted synthesis of highly functionalized benzoxazoles using solid-supported reagents (SSRs)
Radi, Marco,Saletti, Sara,Botta, Maurizio
, p. 4464 - 4466 (2008/09/21)
A one-pot, two-step protocol for the microwave-assisted solid-phase synthesis of substituted benzoxazoles has been developed starting from different polymer-bound esters we previously designed as solid-supported reagents (SSRs) for the acylation of amines, alcohols and phenols. The combination of a parallel synthesizer and a microwave reactor allowed to quickly prepare a collection of substituted benzoxaxoles in high purity and satisfactory yields. This protocol is amenable for automation and could be used for the preparation of combinatorial libraries in drug discovery programs.
