119879-91-3

Upstream product

• 119879-90-2 5-(Benzyloxy)-2-bromophenylamine 
• 98-09-9 benzenesulfonyl chloride 
• 1484-26-0 3-(benzyloxy)aniline 

Downstream Products

• 119880-02-3 6-(benzyloxy)-3-(((methanesulfonyl)oxy)methyl)-1-(phenylsulfonyl)indoline 
• 119880-04-5 6-hydroxy-3-(((methanesulfonyl)oxy)methyl)-1-(phenylsulfonyl)indoline 
• 119879-97-9 6-(benzyloxy)-3-(hydroxymethyl)-1-(phenylsulfonyl)indoline 
• 119879-95-7 6-(benzyloxy)-1-(phenylsulfonyl)-3-vinylindoline 
• 119879-99-1 6-hydroxy-3-(hydroxymethyl)-1-(phenylsulfonyl)indoline 
• 119880-01-2 (+/-)-N-(phenylsulfonyl)-1,2,7,7a-tetrahydrocycloprop<1,2-c>indol-4-one 
• 153914-87-5 (3RS)-3-(Acetoxymethyl)-5-(acetylallylamino)-1-(benzenesulfonyl)-6-(benzyloxy)-4-iodo-2,3-dihydro-1H-indole 
• 153914-88-6 (1RS)-6-Acetyl-3-(benzenesulfonyl)-5-(benzyloxy)-1-(acetoxymethyl)-8-methylene-1,2,7,8-tetrahydro-6H-pyrrolo<3,2-e>indole 
• 153914-86-4 (3RS)-3-(Acetoxymethyl)-5-(acetylamino)-1-(benzenesulfonyl)-6-(benzyloxy)-4-iodo-2,3-dihydro-1H-indole 
• 153914-84-2 (3RS)-1-(Benzenesulfonyl)-6-(benzyloxy)-4-iodo-3-(iodomethyl)-5-nitro-2,3-dihydro-1H-indole 
• 153914-85-3 (3RS)-1-(Benzenesulfonyl)-6-(benzyloxy)-3-(hydroxymethyl)-4-iodo-5-nitro-2,3-dihydro-1H-indole 
• 153977-76-5 (3RS)-5-Amino-1-(benzenesulfonyl)-6-(benzyloxy)-4-iodo-3-(hydroxymethyl)-2,3-dihydro-1H-indole 
• 153914-81-9 (3RS)-1-(Benzenesulfonyl)-6-(benzyloxy)-4-iodo-3-(iodomethyl)-2,3-dihydro-1H-indole 
• 112764-67-7 (1RS)-3-(Benzenesulfonyl)-5-(benzyloxy)-1-(hydroxymethyl)-8-methyl-1,2-dihydro-3H-pyrrolo<3,2-e>indole 

Relevant academic research and scientific papers

Synthesis of (±)-N2-(benzenesulfonyl)-CPI, the protected A-unit of the antitumor antibiotic CC-1065, by two metal-initiated cyclizations

A new synthetic route to (±)-N2-(Benzenesulfonyl)-CPI (16), the protected A-unit containing a cyclopropylhexadienone moiety of the highly potent antitumor antibiotic CC-1065 (1), from 5-(benzyloxy)-2- bromophenylamine (3) is described. The key

Synthesis of N-(phenylsulfonyl)-CI, N-((tert-butyloxy)carbonyl)-CI, CI-CDPI 1, and CI-CDPI 2: CC-1065 functional analogues incorporating the parent 1,2,7,7a-tetrahydrocycloprop[1,2-c]indol-4-one (CI) left-hand subunit

Full details of the synthesis of N-(phenylsulfonyl)- and N-((tert-butyloxy)carbonyl)-1,2,7,7a-tetrahydrocycloprop[1,2-c]indol-4-one [N-(phenylsulfonyl)-CI (9) and N-BOC-CI (10)] constituting stable derivatives of the parent cyclopropylcyclohexadienone rin