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3-methyl-1-benzofuran-2-carbaldehyde(SALTDATA: FREE) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1199-07-1 Structure
  • Basic information

    1. Product Name: 3-methyl-1-benzofuran-2-carbaldehyde(SALTDATA: FREE)
    2. Synonyms: 3-methyl-1-benzofuran-2-carbaldehyde(SALTDATA: FREE);3-methyl-1-benzofuran-2-carbaldehyde;2-Benzofurancarboxaldehyde, 3-methyl-
    3. CAS NO:1199-07-1
    4. Molecular Formula: C10H8O2
    5. Molecular Weight: 160.16932
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1199-07-1.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 277.4°Cat760mmHg
    3. Flash Point: 124.4°C
    4. Appearance: /
    5. Density: 1.192g/cm3
    6. Vapor Pressure: 0.00453mmHg at 25°C
    7. Refractive Index: 1.633
    8. Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
    9. Solubility: N/A
    10. CAS DataBase Reference: 3-methyl-1-benzofuran-2-carbaldehyde(SALTDATA: FREE)(CAS DataBase Reference)
    11. NIST Chemistry Reference: 3-methyl-1-benzofuran-2-carbaldehyde(SALTDATA: FREE)(1199-07-1)
    12. EPA Substance Registry System: 3-methyl-1-benzofuran-2-carbaldehyde(SALTDATA: FREE)(1199-07-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1199-07-1(Hazardous Substances Data)

1199-07-1 Usage

Physical state

yellow liquid

Odor

pleasant floral odor

Use

fragrance ingredient in perfumes and other cosmetic products

Use

synthesis of various pharmaceuticals and organic compounds

Toxicity

low to moderate acute toxicity

Effects on human health

no significant adverse effects reported

Effects on the environment

no significant adverse effects reported

Handling and storage

proper procedures should be followed to minimize potential risks.

Check Digit Verification of cas no

The CAS Registry Mumber 1199-07-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,9 and 9 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1199-07:
(6*1)+(5*1)+(4*9)+(3*9)+(2*0)+(1*7)=81
81 % 10 = 1
So 1199-07-1 is a valid CAS Registry Number.
InChI:InChI=1/C10H8O2/c1-7-8-4-2-3-5-9(8)12-10(7)6-11/h2-6H,1H3

1199-07-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-methyl-1-benzofuran-2-carbaldehyde

1.2 Other means of identification

Product number -
Other names 2-formyl-3-methylbenzofuran

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1199-07-1 SDS

1199-07-1Relevant articles and documents

Access to Hetero-Benzyl Scaffolds via Transient-Ligand-Enabled Direct γ-C(sp3)-H Arylation of 3-Methylheteroarene-2-Carbaldehydes

Bhat, Ramakrishna G.,Reddy, Chennakesava,Shaikh, Javed Y.

, p. 6924 - 6934 (2020/06/27)

An efficient and straightforward method has been developed for the synthesis of β-benzyl-substituted 5-membered heterocyclic carbaldehydes via transient directing-group-enabled direct γ-C(sp3)-H arylation of 3-methylheteroarene-2-carbaldehydes. A wide range of 3-methylheteroarene carbaldehydes undergo coupling with a variety of aryl iodides, including less reactive iodo pyridine derivatives to provide a library of highly selective functionalized products in good to excellent yields. Some of these products have been successfully utilized in synthesizing useful synthetic intermediates.

COMPOUNS, COMPOSITIONS AND METHODS OF USE

-

Page/Page column 175; 176, (2018/07/29)

Herein, compounds, compositions and methods for modulating inclusion formation and stress granules in cells related to the onset of neurodegenerative diseases, musculoskeletal diseases, cancer, ophthalmological diseases, and viral infections are described.

Cycloisomerization between Aryl Enol Ether and Silylalkynes under Ruthenium Hydride Catalysis: Synthesis of 2,3-Disubstituted Benzofurans

Ohno, Shohei,Takamoto, Kohei,Fujioka, Hiromichi,Arisawa, Mitsuhiro

, p. 2422 - 2425 (2017/05/12)

Metal-catalyzed cycloisomerization reactions of 1,n-enynes have become conceptually and chemically attractive processes in the search for atom economy, which is a key subject of current research. However, metal-catalyzed cycloisomerization between aryl enol ether and silylalkynes has not been developed. The ruthenium hydride complex catalyzed cycloisomerization between aryl enol ether and silylalkynes is reported to give benzofurans having useful functional groups, vinyl and trimethylsilylmethyl, on the 2- and 3-positions, respectively.

Efficient synthesis of chiral benzofuryl β-amino alcohols via a catalytic asymmetric Henry reaction

Chen, Wei,Zhou, Zhao-Hui,Chen, Hong-Bin

, p. 1530 - 1536 (2017/02/15)

Chiral β-amino alcohol ligands were found effective for the copper(ii)-catalyzed asymmetric Henry reaction of benzofuran-2-carbaldehydes with nitromethane, which led to the formation of (S)-enriched benzofuryl β-nitro alcohols with satisfactory enantioselectivities (up to 98% ee). Using this catalytic protocol, bioactive (S)-benzofuryl β-amino alcohols could be conveniently prepared in short steps.

Preparation of highly functionalised benzofurans from ortho-hydroxyphenones and dichloroethylene: Applications and mechanistic investigations

Schevenels, Florian,Tinant, Bernard,Declercq, Jean-Paul,Markó, István E.

, p. 4335 - 4343 (2013/04/24)

Highly functionalised benzofurans have been prepared from ortho-hydroxyphenones and 1,1-dichloroethylene. The key intermediate, a chloromethylene furan, smoothly rearranged into the corresponding benzofuran carbaldehyde under acidic conditions. Some mechanistic investigations have been performed and several biologically active benzofurans have been synthesised. Copyright

Efficient and connective assembly of highly functionalized benzofurans using o-hydroxyphenones and dichloroethylene

Schevenels, Florian,Marko, Istvan E.

supporting information; experimental part, p. 1298 - 1301 (2012/05/31)

The preparation of highly functionalized benzofurans by a unique and connective transformation is reported. Base-catalyzed condensation of o-hydroxyphenones with 1,1-dichloroethylene generates the corresponding chloromethylene furans. These labile intermediates undergo a facile rearrangement into benzofuran carbaldehydes under mild acidic conditions.

Synthesis and Evaluation of 2-Pyridinone Derivatives as HIV-1-Specific Reverse Transcriptase Inhibitors. 2. Analogues of 3-Aminopyridin-2(1H)-one

Saari, Walfred S.,Wai, John S.,Fisher, Thorsten E.,Thomas, Craig M.,Hoffman, Jacob M.,et al.

, p. 3792 - 3802 (2007/10/02)

A series of nonnulceoside 3-aminopyridin-2(1H)-one derivatives was synthesized and evaluated for HIV-1 RT inhibitory properties.Several analogs proved to be potent and highly selective antagonists with in vitro IC50 values as low as 19 nM in the enzyme assay using rC*dG as template*primer.Two compounds from this series, 3-amino>-5-ethyl-6-methylpyridin-2(1H)-one (34, L-697,639) and the corresponding 4,7-dichloro analogue (37, L-697,661) inhibited the spread of HIV-1 IIIb infection by 95percent in MT4 cell culture at concentrations of 25-50 nM and were selected for clinical trials as antiviral agents.

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